(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

Base Information

• Chemical Name: (perfluorophenyl)(phenyl)iodonium hexafluorophosphate
• CAS No.: 951037-67-5
• Molecular Formula: C₁₂H₅F₅I*F₆P
• Molecular Weight: 516.032
• Mol file: 951037-67-5.mol

Synonyms:(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

Chemical Property of (perfluorophenyl)(phenyl)iodonium hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (perfluorophenyl)(phenyl)iodonium hexafluorophosphate

There total 6 articles about (perfluorophenyl)(phenyl)iodonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

pentafluoro(difluoroiodo)benzene (24973-39-5) + phenyltetrafluorophosphorane (666-23-9) → (perfluorophenyl)(phenyl)iodonium hexafluorophosphate (951037-67-5)

Guidance literature:

In dichloromethane; at -60 ℃;

DOI:10.1016/j.jfluchem.2006.05.008

Reference yield: 53.0%

trimethylphenylsilane (768-32-1) + (hydroxy(tosyloxy)iodo)pentafluorobenzene (111873-52-0) → (perfluorophenyl)(phenyl)iodonium hexafluorophosphate (951037-67-5)

Guidance literature:

trimethylphenylsilane; (hydroxy(tosyloxy)iodo)pentafluorobenzene; In acetonitrile; for 24h; Reflux; Inert atmosphere;

With potassium hexafluorophosphate; In water;

DOI:10.1021/acs.joc.7b01616

Reference yield:

C21H17F5IN2(1+)*F6P(1-) → (perfluorophenyl)(phenyl)iodonium hexafluorophosphate (951037-67-5) + 4-pyrrolidin-1-ylpyridine (2456-81-7)

Guidance literature:

In acetonitrile; at 20 ℃; Equilibrium constant; Inert atmosphere;

DOI:10.1021/jacs.9b12998

upstream raw materials:

pentafluoro(difluoroiodo)benzene

phenyltetrafluorophosphorane

trimethylphenylsilane

(hydroxy(tosyloxy)iodo)pentafluorobenzene

Downstream raw materials:

tert-butylammonium hexafluorophosphate(V)