tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

Base Information

Chemical Name:tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane
CAS No.:1414855-06-3
Molecular Formula:C₂₈H₅₂O₂Si₃
Molecular Weight:504.976
Hs Code.:

Synonyms:tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

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Chemical Property of tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

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Technology Process of tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

There total 6 articles about tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 1414855-05-2
2-[(1R,3R,E)-3-{[(tert-butyldimethylsilyl)oxy]methyl}-2-{[dimethyl(phenyl)silyl]methylene}-3-methylcyclopentyl]propan-2-ol

: 1414855-06-3
tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 - 23 ℃; Inert atmosphere;
DOI:10.1055/s-0032-1316589

Reference yield:

: 121618-70-0,121618-62-0
(S)-2-(tert-butyldimethylsilanyloxymethyl)-2,6-dimethyl-hept-5-enal

: 1414855-06-3
tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / methanol / 0 - 23 °C / Inert atmosphere

2: edetate disodium; oxone; Dimethoxymethane; potassium carbonate; Shi's ketone; borax; tetra(n-butyl)ammonium hydrogensulfate / acetonitrile; water / 1.5 h / 0 °C / Inert atmosphere

3: copper(l) cyanide; boron trifluoride diethyl etherate / tetrahydrofuran / 2 h / -78 °C

4: 2,6-dimethylpyridine / dichloromethane / -78 - 23 °C / Inert atmosphere

With 2,6-dimethylpyridine; borax; oxone; Shi's ketone; Dimethoxymethane; boron trifluoride diethyl etherate; tetra(n-butyl)ammonium hydrogensulfate; copper(l) cyanide; edetate disodium; potassium carbonate; In tetrahydrofuran; methanol; dichloromethane; water; acetonitrile;
DOI:10.1055/s-0032-1316589

Reference yield:

: 1414855-02-9
tert-butyl{[(R)-2-ethynyl-2,6-dimethylhept-5-en-1-yl]oxy}dimethylsilane

: 1414855-06-3
tert-butyl{[(1R,3R,E)-2-{[dimethyl(phenyl)silyl]methylene}-1-methyl-3-{2-[(trimethylsilyl)oxy]propan-2-yl}cyclopentyl]methoxy}dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: edetate disodium; oxone; Dimethoxymethane; potassium carbonate; Shi's ketone; borax; tetra(n-butyl)ammonium hydrogensulfate / acetonitrile; water / 1.5 h / 0 °C / Inert atmosphere

2: copper(l) cyanide; boron trifluoride diethyl etherate / tetrahydrofuran / 2 h / -78 °C

3: 2,6-dimethylpyridine / dichloromethane / -78 - 23 °C / Inert atmosphere

With 2,6-dimethylpyridine; borax; oxone; Shi's ketone; Dimethoxymethane; boron trifluoride diethyl etherate; tetra(n-butyl)ammonium hydrogensulfate; copper(l) cyanide; edetate disodium; potassium carbonate; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1055/s-0032-1316589