5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

Base Information

Chemical Name:5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)
CAS No.:886444-32-2
Molecular Formula:C₅₉H₃₇BrMgN₇O₄Re
Molecular Weight:1198.4
Hs Code.:

Synonyms:5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

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Chemical Property of 5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

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Technology Process of 5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

There total 1 articles about 5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14220-21-4
rhenium(I) pentacarbonyl bromide

: 886444-31-1
5-[4-(4-methyl-2,2'-bipyridine-4'-carboxyamidyl)phenyl]-10,15,20-triphenylporphyrinatomagnesium(II)

: 886444-32-2
5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

Guidance literature:: In toluene; under Ar atm. Re complex and porphyrine in toluene were heated at 70°C for 5 h; react. mixt. was left overnight, solvent was removed in vacuo, residue was washed with MeOH and Et2O;
DOI:10.1021/ja0539802

Reference yield: 85.0%

: 108-99-6
3-Methylpyridine

: 886444-32-2
5-(4-[rhenium(I)tricarbonylbromide-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II)

: 2923-28-6
silver trifluoromethanesulfonate

: 5-(4-[rhenium(I)tricarbonyl(3-picoline)-4-methyl-2,2'-bipyridine-4'-carboxyamidyl]phenyl)-10,15,20-triphenylporphyrinatomagnesium(II) trifluoromethanesulfonate

Guidance literature:: In tetrahydrofuran; under Ar atm. to suspn. Re-Mg complex in THF 3-picoline and AgOTf were added and refluxed for 1 h; solvent was removed in vacuo, residue was dissolved in THF and filtered through alumina plug;
DOI:10.1021/ja0539802