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Product FOB Price Min.Order Supply Ability Supplier
Factory Supply 3-Picoline
Cas No: 108-99-6
No Data 100 Gram 36 Metric Ton/Day Ality Holding Group Limited Contact Supplier
3-Picoline
Cas No: 108-99-6
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
3-picoline
Cas No: 108-99-6
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
High quality 3-Methylpyridine supplier in China
Cas No: 108-99-6
No Data No Data No Data Simagchem Corporation Contact Supplier
Amadis Chemical offer CAS#108-99-6;CAT#A801950
Cas No: 108-99-6
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
β-Picoline
Cas No: 108-99-6
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
3-Methylpyridine
Cas No: 108-99-6
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 2500 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
3-Picoline
Cas No: 108-99-6
No Data 1 Kilogram 10 Kilogram/Day HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier
3-Picoline CAS. NO.108-99-6
Cas No: 108-99-6
No Data 1 Kilogram 1000 Metric Ton/Week Crovell Biotech (Hebei) Co., Ltd. Contact Supplier
TIANFU-CHEM CAS:108-99-6 3-Picoline
Cas No: 108-99-6
No Data 1 Gram 1 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

108-99-6 Usage

Reactivity Profile

3-Picoline may react with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Chemical Properties

colourless liquid

Uses

Solvent; intermediate in the dye and resins industries; in the manufacture of insecticides, waterproofing agents, niacin, and niacinamide.

Health Hazard

HARMFUL if swallowed, inhaled or absorbed through skin. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin. Inhalation may be fatal as a result of spasm, inflammation of larynx and bronchi, chemical pneumonitis and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Uses

A useful precursor to agrochemicals and antidotes for organophosphate poisoning.

Purification Methods

In general, the same methods of purification that are described for 2-methylpyridine can be used. However, 3-methylpyridine often contains 4-methylpyridine and 2,6-lutidine, neither of which can be removed satisfactorily by drying and fractionation, or by using the ZnCl2 complex. Biddiscombe and Handley [J Chem Soc 1957 1954], after steam distillation as for 2-methylpyridine, treated the residue with urea to remove 2,6-lutidine, then azeotropically distilled with acetic acid (the azeotrope had b 114.5o/712mm), and recovered the base by adding excess of aqueous 30% NaOH, drying with solid NaOH and carefully fractionally distilling. The distillate is then fractionally crystallised by slow partial freezing. An alternative treatment [Reithoff et al. Ind Eng Chem (Anal Edn) 18 458 1946] is to reflux the crude base (500mL) for 20-24hours with a mixture of acetic anhydride (125g) and phthalic anhydride (125g) followed by distillation until phthalic anhydride begins to pass over. The distillate is treated with NaOH (250g in 1.5L of water) and then steam distilled. Addition of solid NaOH (250g) to this distillate (ca 2L) led to the separation of 3-methylpyridine which is removed, dried (K2CO3, then BaO) and fractionally distilled. (Subsequent fractional freezing would probably be advantageous.) The hydrochloride has m 85o, and the picrate has m 153o(from Me2CO, EtOH or H2O). [Beilstein 20 III/IV 2710, 20/5 V 506.]

Fire Hazard

Special Hazards of Combustion Products: Vapors may travel considerable distance to a source of ignition and flashback. Forms explosive mixtures in air. Emits toxic fumes under fire conditions.

General Description

Colorless liquid with a sweetish odor .

Air & Water Reactions

Highly Flammable. Water soluble.

108-99-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (P42053)  3-Methylpyridine  99% 108-99-6 P42053-1L 670.41CNY Detail
Aldrich (P42053)  3-Methylpyridine  99% 108-99-6 P42053-500ML 290.16CNY Detail
Aldrich (P42053)  3-Methylpyridine  99% 108-99-6 P42053-25ML 200.07CNY Detail
Aldrich (236276)  3-Methylpyridine  ≥99.5% 108-99-6 236276-50ML 815.49CNY Detail
Alfa Aesar (A14012)  3-Picoline, 99%    108-99-6 2500ml 1060.0CNY Detail
Alfa Aesar (A14012)  3-Picoline, 99%    108-99-6 500ml 252.0CNY Detail
Alfa Aesar (A14012)  3-Picoline, 99%    108-99-6 100ml 194.0CNY Detail

108-99-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-methylpyridine

1.2 Other means of identification

Product number -
Other names BETAP

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-99-6 SDS

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