N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

Base Information

Chemical Name:N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine
CAS No.:1210877-84-1
Molecular Formula:C₂₂H₂₄BNO₂S
Molecular Weight:377.315
Hs Code.:

Synonyms:N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

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Chemical Property of N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

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Technology Process of N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

There total 5 articles about N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 5-bromo-N,N-diphenylthiophen-2-amine

: 1210877-84-1
N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

Guidance literature:: 5-bromo-N,N-diphenylthiophen-2-amine; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 2h; Inert atmosphere;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

Reference yield:

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 174904-78-0
2-(N,N-diphenylamino)thiophene

: 1210877-84-1
N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

Guidance literature:: 2-(N,N-diphenylamino)thiophene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/cm903542v

Reference yield:

: 122-39-4
diphenylamine

: 1210877-84-1
N,N-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-thiophene-2-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium t-butanolate; palladium diacetate; tri-tert-butyl phosphine / toluene / 12 h / 110 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

2.2: 1 h / -78 °C / Inert atmosphere

With n-butyllithium; tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In tetrahydrofuran; toluene;