triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

Base Information

Chemical Name:triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane
CAS No.:918637-21-5
Molecular Formula:C₂₇H₄₅NO₂SSi
Molecular Weight:475.811
Hs Code.:

Synonyms:triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

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Chemical Property of triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

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Technology Process of triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

There total 5 articles about triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 918637-18-0
triethyl((3R,4S,Z)-3-isopropyl-1-[(S)-N-methyl-S-phenylsulfonimidoyl]octa-1,7-dien-4-yloxy)triethylsilane

: 106-95-6
allyl bromide

: 918637-21-5
triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

Guidance literature:: triethyl((3R,4S,Z)-3-isopropyl-1-[(S)-N-methyl-S-phenylsulfonimidoyl]octa-1,7-dien-4-yloxy)triethylsilane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;

allyl bromide; In tetrahydrofuran; hexane; at -45 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield:

: 172748-29-7
(+)-(E,S)-4-methyl-1-(N-methyl-S-phenylsulfonimidoyl)-pent-2-ene

: 918637-21-5
triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 2 h / -78 - 20 °C / Inert atmosphere

1.3: 2.75 h / -78 °C / Inert atmosphere

2.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere

2.2: 20 h / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

3.2: 3 h / -45 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-16-8
(3R,4S,Z)-3-isopropyl-1-[(S)-N-methyl-S-phenylsulfonimidoyl]octa-1,7-dien-4-ol

: 918637-21-5
triethyl((5S,6R,7E)-6-isopropyl-8-[(S)-N-methyl-S-phenylsulfonimidoyl]undeca-1,7,10-trien-5-yloxy)triethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere

1.2: 20 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

2.2: 3 h / -45 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1002/chem.201103060