3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Base Information

Chemical Name:3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
CAS No.:1407188-06-0
Molecular Formula:C₄₄H₄₄BrF₂₆NO₆S₂
Molecular Weight:1320.83
Hs Code.:

3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Synonyms:3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

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Chemical Property of 3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

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Technology Process of 3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

There total 7 articles about 3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 60070-06-6
1,2-bis(bromomethyl)-4,5-dimethylbenzene

: 1407187-99-8
1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

: 1407188-06-0
3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1021/ol302748h

Reference yield:

: 1407187-91-0
3-(N-dodecyl-2-hydroxyacetamido)phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

: 1407188-06-0
3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / -78 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: dichloromethane / 16 h / Inert atmosphere

2.2: 1 h / Inert atmosphere

2.3: 6 h / 20 °C / Inert atmosphere

3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

4.1: potassium carbonate / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With oxalyl dichloride; potassium carbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol302748h

Reference yield:

: 32848-18-3
1,3-phenylene bis(1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate)

: 1407188-06-0
3-(2-(bromomethyl)-4,5-dimethylbenzyl)-1-dodecyl-3-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfonyl)-2-oxoindolin-6-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Guidance literature:: Multi-step reaction with 6 steps

1.1: palladium diacetate; 4a,9a-dihydro-9,9-dimethyl-4,5-bis(diphenylphosphino)-xanthene; potassium phosphate; toluene / 24 h / 110 °C / Inert atmosphere; Molecular sieve; Microwave irradiation

2.1: triethylamine / dichloromethane / 0 - 20 h / Inert atmosphere

2.2: 20 °C / Inert atmosphere

3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / -78 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

4.1: dichloromethane / 16 h / Inert atmosphere

4.2: 1 h / Inert atmosphere

4.3: 6 h / 20 °C / Inert atmosphere

5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

6.1: potassium carbonate / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With potassium phosphate; 4a,9a-dihydro-9,9-dimethyl-4,5-bis(diphenylphosphino)-xanthene; oxalyl dichloride; palladium diacetate; potassium carbonate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; toluene; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol302748h