60070-06-6Relevant academic research and scientific papers
Arene Substitution Design for Controlled Conformational Changes of Dibenzocycloocta-1,5-dienes
Adams, Ralph W.,Alam, Todd M.,Bustamante, Jacqueline,Fu, Wenxin,Li, Jiachen,Lien, Thanh,Liu, Yi,Lu, Jennifer Q.,Stokes, Benjamin J.,Teat, Simon J.,Yang, Weitao
, p. 16651 - 16660 (2020)
We report that an agile eight-membered cycloalkane can be stabilized by fusing a benzene ring on each side, substituted with proper functional groups. The conformational change of dibenzocycloocta-1,5-diene (DBCOD), a rigid?flexible?rigid organic moiety,
Organic thin film transistors based on 2,3-dimethylpentacene and 2,3-dimethyltetracene
Valiyev, Famil,Huang, Chi-Wei,Sheu, Hwo-Shuenn,Tao, Yu-Tai
, p. 1504 - 1511 (2012)
2,3-Dimethylpentacene (DMP) and 2,3-dimethyltetracene (DMT) were synthesized, characterized and employed as the channel material in the fabrication of thin-film transistors. The two methyl groups increase the chemical stability of the compounds versus the
Methyl and Dimethyl o-Xylenyl-Substituted Fullerene Acceptors for Polymer Solar Cells
Kim, Hee Un,Park, Jong Baek,Grimsdale, Andrew C.,Hwang, Do-Hoon
, p. 1017 - 1027 (2015/09/28)
A series of fullerene derivatives based on methyl- and dimethyl-substituted o-xylenyl groups were synthesized via Diels-Alder reaction from fullerene (C60) and dienes derived from α,α′-dibromo-o-xylene derivatives. The synthesized 1-methyl-4,5-
Closely stacked oligo(phenylene ethynylene)s: Effect of π-stacking on the electronic properties of conjugated chromophores
Jagtap, Subodh P.,Mukhopadhyay, Sukrit,Coropceanu, Veaceslav,Brizius, Glen L.,Bredas, Jean-Luc,Collard, David M.
, p. 7176 - 7185 (2012/06/15)
In this work, a bicyclo[4.4.1]undecane scaffold is used to hold oligo(phenylene ethynylene) units in a cofacially stacked arrangement along the entire length of the conjugated units. We study the impact that the resulting strong interchain interactions ha
Phase tag-assisted synthesis of benzo[ b ]carbazole end-capped oligothiophenes
Levick, Matthew T.,Coote, Susannah C.,Grace, Iain,Lambert, Colin,Turner, Michael L.,Procter, David J.
supporting information, p. 5744 - 5747 (2013/01/15)
The introduction and removal of a phase tag have been used to trigger cyclization events in a new synthesis of benzo[b]carbazoles. The approach has been exploited in a tag-assisted approach to new benzo[b]carbazole end-capped oligothiophenes for prelimina
Fullerene Derivatives and Organic Electronic Device Comprising the Same
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Page/Page column 9, (2012/01/14)
The present invention relates to fullerene derivatives and an organic electronic device using the same, and more specifically, to a novel fullerene derivative incorporating an aromatic fused ring compound and to an organic electronic device with excellent
Regioselective bromomethylation of 1,2-dialkylbenzenes
Garg, Nupur,Lee, T. Randall
, p. 310 - 312 (2007/10/03)
This paper describes a systematic exploration of the regioselective bromomethylation of 1,2-dialkylbenzenes as a function of the reaction temperature and the chain length of the alkyl groups. At both 80 and 110 °C, bromomethyl groups can be introduced into the 4 and 5 positions of 1,2-dialkylbenzenes with high selectivity when the alkyl chains consist of two or more carbon atoms.
Process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds and new 1,4-disubstituted bicyclic compounds
-
, (2015/05/06)
The present invention provides a new process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds by reacting a 1,2-bis-cyanomethyl-benzene or 2,3-bis-cyanomethyl-naphthalene with glyoxal in the presence of a base and a solvent as well as new 1,4-disubstituted bicyclic compounds.
