dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II)

Base Information

• Chemical Name: dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II)
• CAS No.: 364041-97-4
• Molecular Formula: C₄₇H₃₉Cl₂N₃OP₂Ru
• Molecular Weight: 895.77
• Mol file: 364041-97-4.mol

Synonyms:dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II)

Chemical Property of dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II)

There total 1 articles about dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + N-(2-pyridyl)pyridine-2'-carboxamide (53995-57-6) → dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II) (364041-97-4)

Guidance literature:

In ethanol; equimol., refluxed for 2 h; cooled, ppt. filtered, washed thoroughly (ethanol), dried (CaCl2); elem.anal.;

DOI:10.1016/S0277-5387(01)00706-9

Reference yield: 94.0%

2-(aminoethyl)pyridine (2706-56-1) + dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II) (364041-97-4) + sodium perchlorate → [2-(N-(2-pyridyl)carbamoyl)-pyridine]bis-triphenylphosphine(2-(2-aminoethyl)pyridine)ruthenium(II) perchlorate

Guidance literature:

With triethylammonium; In ethanol; equimol., refluxed for 2 h, filtered, concd., cooled, aq. NaClO4 added; ppt. filtered, wached thoroughly (water), dried (CaCl2); elem. anal.;

DOI:10.1016/S0277-5387(01)00706-9

Reference yield: 91.0%

1,10-Phenanthroline (66-71-7) + dichlorobis-triphenylphosphine[2-(N-(2-pyridinium-2-yl)-carbamoyl-N(-))-pyridine]ruthenium(II) (364041-97-4) + sodium perchlorate → [2-(N-(2-pyridyl)carbamoyl)-pyridine]bis-triphenylphosphine(1,10-phenanthroline)ruthenium(II) perchlorate (364042-01-3)

Guidance literature:

With triethylammonium; In ethanol; equimol., refluxed for 2 h, filtered, concd., cooled, aq. NaClO4 added; ppt. filtered, wached thoroughly (water), dried (CaCl2); elem. anal.;

DOI:10.1016/S0277-5387(01)00706-9

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

N-(2-pyridyl)pyridine-2'-carboxamide

Downstream raw materials:

[2-(N-(2-pyridyl)carbamoyl)-pyridine]bis-triphenylphosphine(2,2'-bipyridine)ruthenium(II) perchlorate

[2-(N-(2-pyridyl)carbamoyl)-pyridine]bis-triphenylphosphine(1,10-phenanthroline)ruthenium(II) perchlorate