1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene

Base Information

• Chemical Name: 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene
• CAS No.: 71106-34-8
• Molecular Formula: C₁₂H₂₂OSi
• Molecular Weight: 210.392
• Mol file: 71106-34-8.mol

Synonyms:1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene

Chemical Property of 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene

There total 2 articles about 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexenone (930-68-7) + tert-butyldimethylsilyl chloride (18162-48-6) → 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene (71106-34-8)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;

DOI:10.1016/S0040-4039(00)81758-X

Reference yield:

cyclohexenone (930-68-7) → 1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene (71106-34-8)

Guidance literature:

DOI:10.1016/S0040-4039(00)85919-5

Reference yield: 76.0%

1-<(tert-butyldimethylsilyl)oxy>-1,5-cyclohexanediene (71106-34-8) → 1-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyl-hydroperoxide (87258-12-6)

Guidance literature:

With dihydrogen peroxide; trifluoroacetic acid; In diethyl ether; for 3h; Ambient temperature;

DOI:10.1016/S0040-4039(00)81758-X

upstream raw materials:

cyclohexenone

tert-butyldimethylsilyl chloride

Downstream raw materials:

tert-Butyl-dimethyl-[(1S,3R,4R)-3-(4-nitro-phenyl)-2-selena-bicyclo[2.2.2]oct-5-en-6-yloxy]-silane

tert-Butyl-dimethyl-[(1R,3S,4S)-3-(4-nitro-phenyl)-2-selena-bicyclo[2.2.2]oct-5-en-5-yloxy]-silane

tert-butyldimethyl(phenoxy)silane

4-bromo-benzenesulfonic acid amide