4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside
CAS No.:1311293-55-6
Molecular Formula:C₄₀H₃₉FO₅S
Molecular Weight:650.811
Hs Code.:

Synonyms:4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

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Chemical Property of 4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

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Technology Process of 4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

There total 5 articles about 4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 405-31-2
bis(4-fluorophenyl)disulfide

: (2,3,4,6-tetra-O-benzyl-2-β-D-glucopyranosyl)tri-n-butylstannane

: 1311293-55-6
4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

Guidance literature:: With copper(l) chloride; In 1,2-dichloro-ethane; m-xylene; at 130 ℃; for 96h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jacs.8b11211

Reference yield:

: 96158-81-5
C₁₂H₁₅FO₅S

: 100-39-0
benzyl bromide

: 1311293-55-6
4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 24h;
DOI:10.1002/anie.201100854

Reference yield:

: 371-42-6
4-Fluorothiophenol

: 1311293-55-6
4-fluorophenyl 2,3,4,6-tetrakis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane / 6 h / 0 - 20 °C

2: sodium methylate / methanol / 8 h

3: sodium hydride / N,N-dimethyl-formamide / 24 h / 0 - 20 °C

With boron trifluoride diethyl etherate; sodium methylate; sodium hydride; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/anie.201100854