phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Base Information

Chemical Name:phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate
CAS No.:389805-78-1
Molecular Formula:C₂H₃O₂*C₁₁H₂₄B₁₀ISi
Molecular Weight:478.456
Hs Code.:

Synonyms:phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Suppliers and Price of phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

There total 2 articles about phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 18971-67-0
1,2-dicarba-closo-dodecaboran⁽¹²⁾-yl-1-trimethylsilane

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 389805-78-1
phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; (N2); addn. of a soln. of lithium compd. in hexane to a soln. of boron compd. in Et2O at 0°C, warming to room temp., stirring for 6 h, addn. to a soln. of iodine compd. in Et2O at -78°C, warming to roomtemp., stirring for 6 h; evapn., washing with hexane, extn. with CH2Cl2;

Reference yield: 46.0%

: 18971-67-0
1,2-dicarba-closo-dodecaboran⁽¹²⁾-yl-1-trimethylsilane

: phenyliodine(III) diacetate

: 389805-78-1
phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

Guidance literature:: With n-BuLi; In diethyl ether; hexane; ether soln. of carborane mixed with n-BuLi in hexane at 0°C; warmed to room temp. and stirred for 6 h, soln. added dropwise to ether soln. of phenyl iodonium acetate at -78°C, warmed to room temp., stirred for 6 h; evapd., residue washed (hexane), extd. (CH2Cl2), ele. anal.;
DOI:10.1039/b107343e

Reference yield: 84.0%

: 19064-76-7,94664-76-3
N-benzylidene-4-methoxyaniline oxide

: 389805-78-1
phenyl-[o-(trimethylsilyl)carboranyl]iodonium acetate

: C₁₆H₂₃B₁₀NO₂

Guidance literature:: With cesium fluoride; In tetrahydrofuran; at 25 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.5b09074