[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

Base Information

Chemical Name:[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6
CAS No.:201543-21-7
Molecular Formula:C₄₆H₄₆ClFeP₂Ru*F₆P
Molecular Weight:998.153
Hs Code.:

Synonyms:[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

Suppliers and Price of [(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

There total 1 articles about [(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: sodium hexaflorophosphate

: [RuCl₂(hexamethylbenzene)]2

: 201543-21-7
[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

Guidance literature:: In dichloromethane; acetone; N2-atmosphere; addn. of excess NaPF6 to mixt. of Ru-complex with 2 equiv. of Fe-complex (in CH2Cl2/Me2CO=3:2) at room temp., stirring for 2 h; solvent removal (reduced pressure), extn. into CH2Cl2, concn., crystn. on ether addn.; elem. anal.;
DOI:10.1016/S0022-328X(98)00499-9

Reference yield: 88.0%

: 201543-21-7
[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

: 540-72-7
sodium thiocyanide

: 717901-49-0
[(η6-hexamethylbenzene)Ru(1,1'-bis(diphenylphosphino)ferrocene)(NCS)]PF6

Guidance literature:: In methanol; (N2); refluxing a mixt. of ruthenium complex with NaNCS in MeOH for 23 h; filtration, washing with MeOH, ether, drying in vac., evapn. of filtrate, recrystn. (CH2Cl2/hexane 1:4); elem. anal.;
DOI:10.1016/j.jorganchem.2004.03.022

Reference yield: 67.0%

: 201543-21-7
[(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6

: 540-72-7
sodium thiocyanide

: [(η6-hexamethylbenzene)Ru(NCS)2]2(μ-1,1'-bis(diphenylphosphino)ferrocene)

Guidance literature:: In acetonitrile; (N2); stirring a mixt. of ruthenium complex and excess NaNCS in acetonitrile for 2-3 d; filtration, concn., addn. of ether, cooling to 0-5°C for 1 h; elem. anal.;
DOI:10.1016/j.jorganchem.2004.03.022