3-methyl-1-(trimethylsilyl)allene

Base Information

• Chemical Name: 3-methyl-1-(trimethylsilyl)allene
• CAS No.: 14583-74-5
• Molecular Formula: C₇H₁₄Si
• Molecular Weight: 126.274
• Mol file: 14583-74-5.mol

Synonyms:3-methyl-1-(trimethylsilyl)allene

Chemical Property of 3-methyl-1-(trimethylsilyl)allene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-methyl-1-(trimethylsilyl)allene

There total 4 articles about 3-methyl-1-(trimethylsilyl)allene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

{C5H5(CO)Fe}2(μ-CH3CHCCHSi(CH3)3) → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + [(η(5)-Cp)Fe(CO)]4 + 3-methyl-1-(trimethylsilyl)allene (14583-74-5)

Guidance literature:

With carbon monoxide; In benzene-d6; Irradiation (UV/VIS); Fe complex was photolyzed (black light bulb, emission max. 366 nm) in an CO atmosphere; monitored by NMR;

DOI:10.1021/ja00229a025

Reference yield: 86.0%

{C5H5(CO)Fe}2(μ-CH3CHCCHSi(CH3)3) → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + 3-methyl-1-(trimethylsilyl)allene (14583-74-5)

Guidance literature:

With carbon monoxide; In benzene-d6; Irradiation (UV/VIS); Fe complex was heated at 62°C in an CO atmosphere; monitored by NMR;

DOI:10.1021/ja00229a025

Reference yield: 83.0%

d,l-1-(trimethylsilyl)-3-methoxy-1-butyne (102306-58-1) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + 3-methyl-1-(trimethylsilyl)allene (14583-74-5)

Guidance literature:

at 610 ℃; under 0.01 Torr;

DOI:10.1016/S0040-4039(00)80162-8

upstream raw materials:

d,l-1-(trimethylsilyl)-3-methoxy-1-butyne

Downstream raw materials:

thallium chloride

(Z)-1-(1-(trimethylsilyl)ethyliden)-4,4-dimethyl-2,3,4,5-tetrahydro-benzo[d]azepinium triflate

palladium

2-(3-butynyl)-1-cyclohexanol