Thallous Chloride Tl-201

Base Information

• Chemical Name: Thallous Chloride Tl-201
• CAS No.: 55172-29-7
• Molecular Formula: ClTl
• Molecular Weight: 239.836
• NCI Thesaurus Code: C47750
• RXCUI: 91588
• Wikidata: Q27114831
• Mol file: 55172-29-7.mol

Synonyms:THALLOUS CHLORIDE TL-201;Thallium-201 chloride;Thallous chloride tl 201;Thallous Chloride, Tl-201;CHEBI:32213;3I8Y076A0E;allous Chloride Tl-201;Thallous chloride,tl-201;Thallous Chloride T1-201;thallous chloride, Tl 201;(201)TlCl;(201-Tl)Thallous chloride;Thallium (201Tl) chloride;chloro(201Tl)thallium-201;thallium-201(1+) chloride;UNII-3I8Y076A0E;(201-Tl) Thallous Chloride;Thallous chloride (201TlCl);((201)Tl)thallium monochloride;((201)Tl)thallium(I) chloride;((201)Tl)thallium(1+) chloride;Thallium chloride ((sup 201)TlCl);Thallous chloride Tl 201 [USAN:USP];Thallium chloride ((sup 201)Tl) injection;Q27114831

Chemical Property of Thallous Chloride Tl-201

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C
• PSA: 0.00000
• LogP: 0.68950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 235.9397
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

97% ^*data from raw suppliers

THALLOUS CHLORIDE TI-201 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Cl[Tl]
• Isomeric SMILES: Cl[201Tl]
• Recent ClinicalTrials: Comparison of Diagnostic Rest/Stress SPECT Results for Patients With Myocardial Ischemia and Infarction Using Myoview in Both Single and Dual Isotope Acquisition Approaches

Technology Process of Thallous Chloride Tl-201

There total 225 articles about Thallous Chloride Tl-201 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) + (triphenylphosphine)silver iodide (61026-08-2) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoAgC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. IAgPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

Reference yield: 57.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + (NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoAuC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. ClAuPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

Reference yield: 55.0%

(NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) + tetrameric (triphenylphosphine)copper(I) iodide (47107-74-4) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoCuC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. ICuPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

upstream raw materials:

sodium chloride

trichlorophosphate

hydrogenchloride

thallium(I) perchlorate

Downstream raw materials:

thallium(I) bis(tert-butylamido)phenylborane

thallium(I) bis(isopropylamido)phenylborane

thallium(I) sulfide

sulfur

Refernces

• 1、 Beck, Johannes,Benz, Sebastian. "Crystalline and glassy phases in the ternary system Tl/Bi/Cl: Synthesis and crystal structures of the thallium(I) chloridobismutates(III) Tl3BiCl 6 and TlBi2Cl7". . p. 928 - 935. Retrieved 2010.
• 2、 Ding, Yuqiang,Goddard, Richard,Poerschke, Klaus-Richard. "Cationic dinuclear Pd-allyl-halide complexes with N-heterocyclic carbenes". . p. 439 - 445. Retrieved 2005.
• 3、 Jesus, Ernesto de,Miguel, Amelio Vazquez de,Royo, Pascual,Lanfredi, Anna Maria Manotti,Tiripicchio, Antonio. "Synthesis of and 2>". . p. 2779 - 2784. Retrieved 1990.
• 4、 Moeller, K.. "". . p. 223 - 223. Retrieved 1933.
• 5、 Liu, Shaofeng,Peloso, Riccardo,Pattacini, Roberto,Braunstein, Pierre. "Electrophilic activation and the formation of an unusual Tl +/Cr3+ tetranuclear ion-complex adduct". . p. 7881 - 7883. Retrieved 2010.
• 6、 Rheingold,Incarvito,Trofimenko. "Dihydrobis(4-cyanopyrazol-1-yl)borate, [Bp4CN], a functionalized heteroscorpionate ligand with cross-linking potential". . p. 5569 - 5571. Retrieved 2000.
• 7、 DeRosa,Al-Mutlaq,Crutchley. "Semiconductor properties in an iodine-doped platinum(II) dinuclear complex". . p. 1406 - 1407. Retrieved 2001.
• 8、 Berthet, Jean-Claude,Siffredi, Gerald,Thuery, Pierre,Ephritikhine, Michel. "Synthesis and crystal structure of pentavalent uranyl complexes. the remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions". . p. 3478 - 3494. Retrieved 2009.
• 9、 Gambs, Celine,Consiglio, Giambattista,Togni, Antonio. "Structural aspects of palladium and platinum complexes with chiral diphosphinoferrocenes relevant to the regio- and stereoselective copolymerization of CO with propene". . p. 3105 - 3126. Retrieved 2001.
• 10、 Ara, Irene,Fornies, Juan,Fortuno, Consuelo,Ibanez, Susana,Martin, Antonio,Mastrorilli, Piero,Gallo, Vito. "Unsymmetrical platinum(II) phosphido derivatives: Oxidation and reductive coupling processes involving platinum(III) complexes as intermediates". . p. 9069 - 9080. Retrieved 2008.