(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

Base Information

Chemical Name:(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl
CAS No.:1360939-70-3
Molecular Formula:C₂₂H₁₄Co₂O₈
Molecular Weight:524.335
Hs Code.:

Synonyms:(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

Suppliers and Price of (μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

There total 1 articles about (μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.4%

: 4397-53-9
p-benzyloxybenzaldehyde

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 115570-70-2,1066-26-8
sodium acetylide

: 1360939-70-3
(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

Guidance literature:: In diethyl ether; (N2) soln. benzaldehyde in THF at -50°C was added to suspn. HCCNa inTHF, stirred at 20°C for 6 h, aq. NH4Cl was added at 0°C, extd. with ether, added to Co2(CO)8 in ether, stirred at 20°C for 2 h; soln. was concd. in vacuo, chromy. on silica;
DOI:10.1021/om2006497

Reference yield: 85.4%

: 67-56-1
methanol

: 1360939-70-3
(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

: 1360939-48-5
(μ,η2-3-(4'-benzyloxyphenyl)-3-methoxy-1-propyne)dicobalt hexacarbonyl

Guidance literature:: With HBF₄*Me₂O; In diethyl ether; (N2) HBF4*Me2O was added dropwise to soln.Co complex in ether at -20°C, etheral layer was removed and evapd. in vacuo, cation was suspended in ether at -20°C, MeOH was added dropwise, stirred at 20°C for 1.5 h; react. mixt. was diluted with water, dried over molecular sieves and evapd. to dryness;
DOI:10.1021/om2006497

Reference yield: 68.8%

: 1360939-70-3
(μ,η2-1-(4'-benzyloxyphenyl)-2-propyn-1-ol)dicobalt hexacarbonyl

: d,l-[μ,η2-3,4-bis(4'-benzyloxyphenyl)-1,5-hexadiyne]bis(dicobalt hexacarbonyl)

Guidance literature:: With trifluoromethylsulfonic anhydride; In Dimethyl ether; 1,2-dichloro-ethane; at 83 ℃; for 0.05h; Inert atmosphere; Schlenk technique; Reflux;
DOI:10.1039/c3dt51502h