N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine

Base Information

• Chemical Name: N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine
• CAS No.: 81624-54-6
• Molecular Formula: C₆₂H₅₆N₁₀
• Molecular Weight: 941.194
• Mol file: 81624-54-6.mol

Synonyms:N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine

Chemical Property of N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine

There total 1 articles about N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

benzyl bromide (100-39-0) + N1,N1,N2,N2-tetrakis((1H-benzo[d]imidazol-2-yl)methyl)ethane-1,2-diamine (72583-85-8) → N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine (81624-54-6)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; for 1h; Ambient temperature;

DOI:10.1016/0040-4039(88)85078-0

Reference yield:

N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine (81624-54-6) + copper(ll) bromide (7789-45-9) → Cu(CH2N(CH2C7H4N2CH2C6H5)2)2(2+)*2Br(1-)*2H2O=CuBr2(CH2N(CH2C7H4N2CH2C6H5)2)2*2H2O (81625-59-4)

Guidance literature:

In ethanol; salt was added to refluxing suspn. of ligand, refluxed for several minutes, Cu-ligand molar ratio 1:1; concn., filtration, washing a ppt. with ethanol, diethyl ether;

DOI:10.1021/ja00377a012

Reference yield:

copper(II) perchlorate hexahydrate + N,N,N',N'-tetrakis<(1-benzyl-benzimidazolyl)methyl>-1,2-ethanediamine (81624-54-6) → Cu(CH2N(CH2C7H4N2CH2C6H5)2)2(2+)*2ClO4(1-)*H2O=Cu(ClO4)2(CH2N(CH2C7H4N2CH2C6H5)2)2*H2O (81625-63-0)

Guidance literature:

In ethanol; salt was added to refluxing suspn. of ligand, refluxed for several minutes, Cu-ligand molar ratio 1:1; concn., filtration, washing a ppt. with ethanol, diethyl ether;

DOI:10.1021/ja00377a012

upstream raw materials:

benzyl bromide

N¹,N¹,N²,N²-tetrakis((1H-benzo[d]imidazol-2-yl)methyl)ethane-1,2-diamine

Downstream raw materials:

Cu(CH₂N(CH₂C₇H₄N₂CH₂C₆H₅)2)2⁽²⁺⁾*2ClO₄^(1-)*H₂O=Cu(ClO₄)2(CH₂N(CH₂C₇H₄N₂CH₂C₆H₅)2)2*H₂O

Cu(CH₂N(CH₂C₇H₄N₂CH₂C₆H₅)2)2⁽²⁺⁾*2Br^(1-)*2H₂O=CuBr₂(CH₂N(CH₂C₇H₄N₂CH₂C₆H₅)2)2*2H₂O