S-phenyl 2-(4-nitrophenyl)ethanethioate

Base Information

Chemical Name:S-phenyl 2-(4-nitrophenyl)ethanethioate
CAS No.:100725-78-8
Molecular Formula:C₁₄H₁₁NO₃S
Molecular Weight:273.312
Hs Code.:

Synonyms:S-phenyl 2-(4-nitrophenyl)ethanethioate

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Chemical Property of S-phenyl 2-(4-nitrophenyl)ethanethioate

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Technology Process of S-phenyl 2-(4-nitrophenyl)ethanethioate

There total 5 articles about S-phenyl 2-(4-nitrophenyl)ethanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: phenyl(4-nitrophenylethynyl)sulfane

: 100725-78-8
S-phenyl 2-(4-nitrophenyl)ethanethioate

Guidance literature:: With trifluoroborane diethyl ether; triethylamine tris(hydrogen fluoride); In dichloromethane; at 0 - 20 ℃; for 16h; Inert atmosphere;
DOI:10.3762/bjoc.11.205

Reference yield: 42.0%

: 100-14-1
4-nitrobenzyl chloride

: 108-98-5
thiophenol

: 82102-37-2
9-methyl-9H-fluorene-9-carbonyl chloride

: 100725-78-8
S-phenyl 2-(4-nitrophenyl)ethanethioate

Guidance literature:: 4-nitrobenzyl chloride; thiophenol; With bis(benzonitrile)palladium(II) dichloride; sodium acetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; Inert atmosphere; Glovebox;

9-methyl-9H-fluorene-9-carbonyl chloride; With N-Methyldicyclohexylamine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; tri tert-butylphosphoniumtetrafluoroborate; at 80 ℃; for 18h; Inert atmosphere; Glovebox;
DOI:10.1021/jo5009965

Reference yield:

: 1212-08-4
S-Phenyl benzenethiosulfonate

: 100725-78-8
S-phenyl 2-(4-nitrophenyl)ethanethioate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

1.2: 5 h / 20 °C / Inert atmosphere

2.1: triethylamine tris(hydrogen fluoride); trifluoroborane diethyl ether / dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere

With sodium hexamethyldisilazane; trifluoroborane diethyl ether; triethylamine tris(hydrogen fluoride); In tetrahydrofuran; dichloromethane;
DOI:10.3762/bjoc.11.205