Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4

Base Information

• Chemical Name: Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4
• CAS No.: 433927-23-2
• Molecular Formula: C₁₃H₂₇PRh*C₃₂H₁₂BF₂₄
• Molecular Weight: 1180.46

Synonyms:Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4

Chemical Property of Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4

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Technology Process of Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4

There total 2 articles about Rh(C₅(CH₃)5)H₂P(CH₃)3H⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=Rh(C₅(CH₃)5)H₂P(CH₃)3HB(C₆H₃(CF₃)2)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex + (C5Me5)Rh(PMe3)(H)2 (84624-03-3) → Rh(C5(CH3)5)H2P(CH3)3H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)H2P(CH3)3HB(C6H3(CF3)2)4 (433927-23-2) + (Rh(C5(CH3)5)HP(CH3)3)2H(1+)*B(C6H3(CF3)2)4(1-)=(Rh(C5(CH3)5)HP(CH3)3)2HB(C6H3(CF3)2)4

Guidance literature:

In dichloromethane-d2; Rh-complex in NMR tube was sealed, placed at 233 K, soln. of B-salt in CD2Cl2 was added slowly, warmed for 2-3 min at room temp., cooled to 233 K; monitored by NMR;

DOI:10.1021/ja0165990

Reference yield:

[(C5(CH3)5)(P(CH3)3)Rh(CH3)(dichloromethane)][B(3,5-C6H3(CF3)2)4] (431882-00-7) + hydrogen (1333-74-0) → Rh(C5(CH3)5)P(CH3)3(OH2)H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)P(CH3)3H(H2O)B(C6H3(CF3)2)4 (433927-29-8) + Rh(C5(CH3)5)H2P(CH3)3H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)H2P(CH3)3HB(C6H3(CF3)2)4 (433927-23-2)

Guidance literature:

In dichloromethane-d2; NMR tube was charged with soln. of Rh-complex in CD2Cl2, sealed, placed at 233 K bath, exposed to 1 atm H2 for several min, NMR tube was sealed under ca. 500 Torr of H2, shaken;

DOI:10.1021/ja0165990

Reference yield:

tritium (15086-10-9,14885-60-0) + Rh(C5(CH3)5)H2P(CH3)3H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)H2P(CH3)3HB(C6H3(CF3)2)4 (433927-23-2) → Rh(C5(CH3)5)H2P(CH3)3(3)H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)H2P(CH3)3(3)HB(C6H3(CF3)2)4 + Rh(C5(CH3)5)(3)H2P(CH3)3H(1+)*B(C6H3(CF3)2)4(1-)=Rh(C5(CH3)5)(3)H2P(CH3)3HB(C6H3(CF3)2)4

Guidance literature:

In not given; Rh-complex was exposed with T2 at -40°C for 20-60 min; frozen, T2 was removed, sealed under vac.; monitored by NMR;

DOI:10.1021/ja0165990

upstream raw materials:

[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

hydrogen

(C₅Me₅)Rh(PMe₃)(H)2

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