(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

Base Information

Chemical Name:(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)
CAS No.:252209-08-8
Molecular Formula:C₃₁H₂₁IO₃Ru
Molecular Weight:669.48
Hs Code.:

Synonyms:(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

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Technology Process of (η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

There total 3 articles about (η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 252209-08-8
(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

Guidance literature:: In benzene; N2-atmosphere; excess I2, room temp., 2 h; washing (satd. Na2S2O3), drying (MgSO4), solvent removal, chromy. (SiO2,CH2Cl2);
DOI:10.1016/S0022-328X(99)00350-2

Reference yield:

: 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

: 74-88-4
methyl iodide

: 252209-08-8
(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

Guidance literature:: With H₂; In benzene; exposing Ru-complex to 500 psi H2 at 120°C for 4 h, cooling, addn. of excess MeI, refluxing for 1 h under N2; evapn.;
DOI:10.1016/S0022-328X(99)00350-2

Reference yield:

: 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

: 74-88-4
methyl iodide

: 116363-15-6
(η(5)-2,3,4,5-tetraphenyl-1-methoxycyclopentadienyl)(iodo)dicarbonylruthenium(II)

: 252209-13-5
[Ru(CO)2(C₅(C₆H₅)4O)]2I

: 252209-08-8
(η(5)-2,3,4,5-tetraphenylcyclopentadien-1-ol)(iodo)dicarbonylruthenium(II)

Guidance literature:: In benzene; excess of MeI, refluxing for 5 h; solvent removal (vac.), chromy. (SiO2, CH2Cl2/petroleum ether=1:4, then CH2Cl2, then AcOEt);
DOI:10.1016/S0022-328X(99)00350-2