Trifluoromethanesulfonate

Base Information

• Chemical Name: Trifluoromethanesulfonate
• CAS No.: 37181-39-8
• Deprecated CAS: 1375612-01-3,1425793-85-6,1429219-49-7,1610340-80-1,460315-00-8,627050-95-7,85695-84-7,886757-21-7
• Molecular Formula: CF₃O₃S
• Molecular Weight: 149.07
• DSSTox Substance ID: DTXSID70110004
• Nikkaji Number: J232.002I
• Wikidata: Q27121260

Synonyms:AgOTf cpd;Al(OTf)3;aluminum triflate;As(otf)2;cerium triflate;Cu(OTf)2;cupric trifluoromethanesulfonate;Eu(OTf)3;In(OTf)3;indium triflate;mercury(II) trifluoromethanesulfonate;samarium triflate;silver triflate;silver trifluoromethanesulfonate;TFMSA cpd;triflic acid;trifluoromethanesulfonate;trifluoromethanesulfonic acid;trifluoromethanesulfonic acid, aluminum salt;trifluoromethanesulfonic acid, barium salt;trifluoromethanesulfonic acid, cerium (+3) salt;trifluoromethanesulfonic acid, cupric salt;trifluoromethanesulfonic acid, indium salt;trifluoromethanesulfonic acid, lanthanum (+3) salt;trifluoromethanesulfonic acid, lithium salt;trifluoromethanesulfonic acid, samarium salt;trifluoromethanesulfonic acid, silver (+1) salt;trifluoromethanesulfonic acid, zinc salt;zinc triflate

Chemical Property of Trifluoromethanesulfonate

Chemical Property:

• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 148.95202452
• Heavy Atom Count: 8
• Complexity: 145

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-]

Technology Process of Trifluoromethanesulfonate

There total 9 articles about Trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-nitrophenolate (14609-74-6) + methyl trifluoromethanesulfonate (333-27-7) → para-methoxynitrobenzene (100-17-4) + trifluoromethanesulfonate (37181-39-8)

Guidance literature:

at 42 ℃; Rate constant;

Reference yield:

hydroxide + trifluoromethanesulfonic acid trichlormethylester (24401-22-7) → trifluoromethanesulfonate (37181-39-8) + chloride (16887-00-6) + carbonate(2-) (3812-32-6)

Guidance literature:

In water; byproducts: H2O;

Reference yield:

thiophenolate (13133-62-5) + methyl trifluoromethanesulfonate (333-27-7) → methyl-phenyl-thioether (100-68-5) + trifluoromethanesulfonate (37181-39-8)

Guidance literature:

at 42 ℃; Rate constant;

upstream raw materials:

2,6-dimethylbenzoic trifluoromethanesulfonic anhydride

2,4,6-Trimethylbenzoesaeure-trifluomethansulfonsaeure-anhydrid

4-Methoxy-2,6-dimethylbenzoesaeure-trifluormethansulfonsaeure-anhydrid

2,6-Dimethyl-4-nitrobenzoesaeure-trifluormethansulfonsaeure-anhydrid

Downstream raw materials:

2,4,6-Trimethylbenzoesaeure-trifluomethansulfonsaeure-anhydrid

2,6-dimethylbenzoic trifluoromethanesulfonic anhydride

4-Chlor-2,6-dimethylbenzoesaeure-trifluormethansulfonsaeure-anhydrid

4-Methoxy-2,6-dimethylbenzoesaeure-trifluormethansulfonsaeure-anhydrid

Refernces

Synthesis of marine natural product (-)-pericosine e

10.1021/ol501631r

The research focuses on the first synthesis of (?)-pericosine E, a marine natural product metabolite derived from the sea hare Aplysia kurodai. The study developed efficient and regioselective synthetic procedures for key intermediates, specifically anti- and syn-epoxides 9 and 10. The synthesis involved the use of anti-epoxidation of diene 12 with TFDO and bromohydrination of 12 with NBS in a CH3CN/H2O solvent system. The research compared the specific optical rotations of synthetic and natural 6 to confirm the absolute configuration of the naturally occurring enantiomer. The experiments utilized various reactants, including (?)-shikimic acid, alcohol 13, triflate 14, CsOAc, DMF, NBS, LHMDS, THF, HCl, and BF3?Et2O, among others. Analyses were conducted using techniques like 1H?1H COSY, NOESY, HSQC, and HMBC to establish the regio- and stereochemistry of the products and byproducts. The study concluded with the successful synthesis of (?)-pericosine E and the determination of its absolute configuration, which was found to match that of the naturally preferred enantiomer.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 37181-39-8 trifluoromethanesulfonate

Send

Send

Metric Ton KG G Pound L ML

Send

Send