exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

Base Information

Chemical Name:exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride
CAS No.:862902-41-8
Molecular Formula:C₁₇H₁₆O₆
Molecular Weight:316.31
Hs Code.:

Synonyms:exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

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Chemical Property of exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

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Technology Process of exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

There total 3 articles about exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 108-31-6
maleic anhydride

: 201279-54-1
(R)-(+)-2-(1-benzoyloxyethyl)furan

: 862902-41-8
exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

: exo,exo-(1R)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

Guidance literature:: maleic anhydride; (R)-(+)-2-(1-benzoyloxyethyl)furan; at 20 ℃; for 25h;

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; at 20 ℃; for 10h;
DOI:10.1016/j.bmc.2005.05.013

Reference yield:

: 27948-61-4
(R)-(+)-1-(2-furyl)ethanol

: 862902-41-8
exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

2.1: 25 h / 20 °C

2.2: 36 percent / H₂ / Pd-C / tetrahydrofuran / 10 h / 20 °C

With dmap; triethylamine; In dichloromethane; 2.1: Diels-Alder reaction;
DOI:10.1016/j.bmc.2005.05.013

Reference yield:

: 98-88-4
benzoyl chloride

: 862902-41-8
exo,exo-(1S)-1-((1R)-1-benzoyloxyethyl)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

2.1: 25 h / 20 °C

2.2: 36 percent / H₂ / Pd-C / tetrahydrofuran / 10 h / 20 °C

With dmap; triethylamine; In dichloromethane; 2.1: Diels-Alder reaction;
DOI:10.1016/j.bmc.2005.05.013