{W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}

Base Information

• Chemical Name: {W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}
• CAS No.: 113471-51-5
• Molecular Formula: C₁₈H₄₈Cl₃P₆S₄W₃*C₂₄H₂₀B
• Molecular Weight: 1555.83

Synonyms:{W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}

Chemical Property of {W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}

There total 2 articles about {W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

sodium hydrogen sulfide + 1,2-bis(dimethylphosphanyl)ethane (23936-60-9) + sodium tetraphenyl borate (143-66-8) + tungsten(IV) chloride (13470-13-8) → {W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}(1+)*B(C6H5)4(1-)={W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}{B(C6H5)4} (113471-51-5)

Guidance literature:

In tetrahydrofuran; methanol; NaHS added to a suspn. of WCl4 in thf, addn. of MeOH, P-compn. introduced, refluxed for 2 h; cooled to room temp., ppt. separated by filtration under Ar, soln. adsorbed (silica gel), washed (acetone), pptd. by addn. of NaBPh4;

DOI:10.1021/ja00194a027

Reference yield:

W3S4H3(P(CH3)2C2H4P(CH3)2)3(1+)*B(C6H5)4(1-)={W3S4H3(P(CH3)2C2H4P(CH3)2)3}{B(C6H5)4} + benzoyl chloride (98-88-4) → {W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}(1+)*B(C6H5)4(1-)={W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}{B(C6H5)4} (113471-51-5)

Guidance literature:

In tetrahydrofuran; thf-soln. reacted with excess of PhCOCl, stirred for 3 h;

DOI:10.1021/ja00194a027

Reference yield: 70.0%

lithium borohydride + {W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}(1+)*B(C6H5)4(1-)={W3S4Cl3(P(CH3)2CH2CH2P(CH3)2)3}{B(C6H5)4} (113471-51-5) → W3S4H3(P(CH3)2C2H4P(CH3)2)3(1+)*B(C6H5)4(1-)={W3S4H3(P(CH3)2C2H4P(CH3)2)3}{B(C6H5)4}

Guidance literature:

In tetrahydrofuran; W-compd. was reacted with LiBH4 under Ar in thf; soln. filtered, filtrate combined (ether), cooled to -10°C, solid formed, washed (ether), dried (vac.);

DOI:10.1021/ja00194a027

upstream raw materials:

1,2-bis(dimethylphosphanyl)ethane

sodium tetraphenyl borate

tungsten(IV) chloride

benzoyl chloride

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 113471-51-5 {W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={W₃S₄Cl₃(P(CH₃)2CH₂CH₂P(CH₃)2)3}{B(C₆H₅)4}

Send

Send

Metric Ton KG G Pound L ML

Send

Send