(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

Base Information

Chemical Name:(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide
CAS No.:145088-73-9
Molecular Formula:C₃₀H₂₆BrO₃P₂Re
Molecular Weight:762.593
Hs Code.:

Synonyms:(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

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Chemical Property of (fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

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Technology Process of (fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

There total 1 articles about (fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 14220-21-4
rhenium(I) pentacarbonyl bromide

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 145088-73-9
(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

Guidance literature:: In benzene; Re-compd. and dppp were mixed (molar ratio about 1:1) with benzene and refluxed und argon for about 16 h;; the solvent was removed in a rotary-evaporator; elem. anal.;;
DOI:10.1016/0022-328X(92)80053-Z

Reference yield: 93.0%

: 14104-20-2
silver tetrafluoroborate

: 145088-73-9
(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

: 145088-72-8
((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

Guidance literature:: With CO; In dichloromethane; a slight excess of AgBF4 was added to a soln. of the Re-compd. in refluxing CH2Cl2 while a stream of CO was pased through the soln. for 16 h (all operations were made under Ar);; the soln. was cooled and filtered through a pad of celite; the filtrate was concd., a small amt. of ether added, and the ppt. dried in vac.; elem. anal.;;
DOI:10.1016/0022-328X(92)80053-Z

Reference yield: 32.0%

: tetrabutylammonium octahydrotriborate

: 145088-73-9
(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

: [Re(CO)2((C₆H₅)2P(CH₂)3P(C₆H₅)2)(B₃H₈)]

Guidance literature:: In dichloromethane; Irradiation (UV/VIS); under dry N2; metal complex and boron compd. added to CH2Cl2 in a Cariustube, cooled to 77 K, tube evacuated and sealed, irradiation (medium po wer Hg UV lamp) for 20 h; solvent removed, column chromy. (Florisil, CH2Cl2/hexane (1/4)); elem. anal.;
DOI:10.1016/S0277-5387(03)00289-4