Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

Base Information

Chemical Name:Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester
CAS No.:693825-13-7
Molecular Formula:C₁₁H₁₃F₃O₃S
Molecular Weight:282.284
Hs Code.:

Synonyms:Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

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Chemical Property of Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

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Technology Process of Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

There total 1 articles about Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 6485-40-1,2244-16-8
(R)-Carvone

: 693825-13-7
Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

Guidance literature:: (R)-Carvone; With lithium diisopropyl amide; at -78 ℃;

N,N-phenylbistrifluoromethane-sulfonimide;
DOI:10.1021/jo0357667

Reference yield: 75.0%

: 6414-69-3
ethyl 3-iodopropanoate

: 693825-13-7
Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

: 693825-20-6
3-((R)-3-Isopropenyl-6-methyl-cyclohexa-1,5-dienyl)-propionic acid ethyl ester

Guidance literature:: ethyl 3-iodopropanoate; With zinc copper;

Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl acetamide; benzene; at 60 ℃;
DOI:10.1021/jo0357667

Reference yield:

: 693825-13-7
Trifluoro-methanesulfonic acid (R)-3-isopropenyl-6-methyl-cyclohexa-1,5-dienyl ester

: 693825-26-2
3-((R)-3-Isopropenyl-6-methyl-cyclohexa-1,5-dienyl)-propionic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: Zn(Cu)

1.2: 75 percent / Pd(PPh₃)4 / benzene; N,N-dimethyl-acetamide / 60 °C

2.1: 97 percent / LiOH / tetrahydrofuran; H₂O / 20 °C

With lithium hydroxide; zinc copper; In tetrahydrofuran; water; 1.2: Negishi cross-coupling;
DOI:10.1021/jo0357667