(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Base Information

Chemical Name:(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol
CAS No.:116306-86-6
Molecular Formula:C₂₈H₄₂O₃S₂Si
Molecular Weight:518.857
Hs Code.:

Synonyms:(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Suppliers and Price of (2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

There total 3 articles about (2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 77-76-9
2,2-dimethoxy-propane

: 116306-85-5
(2S,4R)-1-O-t-butyldiphenylsilyl-5,5-bis(ethylthio)-1,2,4-pentanetriol

: 116306-86-6
(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Guidance literature:: With sulfuric acid; In acetone; for 0.333333h; Ambient temperature;
DOI:10.1246/bcsj.60.4005

Reference yield:

: 3396-71-2
3-deoxy-1,2-O-isopropylidene-α-D-ribofuranose

: 116306-86-6
(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / boron trifluoride etherate / 2 h / Ambient temperature

2: 92 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

3: 100 percent / 1.0 percent H₂SO₄ / acetone / 0.33 h / Ambient temperature

With 1H-imidazole; sulfuric acid; boron trifluoride diethyl etherate; In N,N-dimethyl-formamide; acetone;
DOI:10.1246/bcsj.60.4005

Reference yield:

: 116306-84-4
(2S,4R)-5,5-bis(ethylthio)-1,2,4-pentanetriol

: 116306-86-6
(2S,4R)-1-O-(t-butyldiphenylsilyl)-5,5-bis(ethylthio)-2,4-O-isopropylidene-1,2,4-pentanetriol

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

2: 100 percent / 1.0 percent H₂SO₄ / acetone / 0.33 h / Ambient temperature

With 1H-imidazole; sulfuric acid; In N,N-dimethyl-formamide; acetone;
DOI:10.1246/bcsj.60.4005