1-(perfluorophenyl)adamantane

Base Information

• Chemical Name: 1-(perfluorophenyl)adamantane
• CAS No.: 74867-23-5
• Molecular Formula: C₁₆H₁₅F₅
• Molecular Weight: 302.287
• Mol file: 74867-23-5.mol

Synonyms:1-(perfluorophenyl)adamantane

Chemical Property of 1-(perfluorophenyl)adamantane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-(perfluorophenyl)adamantane

There total 6 articles about 1-(perfluorophenyl)adamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-Adamantyl bromide (768-90-1) + potassium 2,3,4,5,6-pentafluorobenzoate (58521-27-0) → 1-(perfluorophenyl)adamantane (74867-23-5)

Guidance literature:

With copper(l) iodide; In diethylene glycol dimethyl ether; at 130 ℃; for 24h; Inert atmosphere;

DOI:10.1002/anie.200904916

Reference yield: 89.0%

Hexafluorobenzene (392-56-3) + 1-Adamantanecarboxylic acid (828-51-3) → 1-(perfluorophenyl)adamantane (74867-23-5)

Guidance literature:

With Ir(dFFppy)₂(dtbbpy)PF₆; lithium carbonate; In dimethyl sulfoxide; at 35 ℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;

DOI:10.1002/anie.202015596

Reference yield: 30.0%

Hexafluorobenzene (392-56-3) + 1-iodoadamantane (768-93-4) → 1-(perfluorophenyl)adamantane (74867-23-5)

Guidance literature:

With 2,4,5,6‐tetra‐9H‐carbazol‐9‐yl‐1,3‐benzenedicarbonitrile; triethylamine; In dimethyl sulfoxide; for 24h; Inert atmosphere; Sealed tube; Irradiation;

DOI:10.1021/acs.orglett.1c04267

upstream raw materials:

1-Adamantyl bromide

potassium 2,3,4,5,6-pentafluorobenzoate

1-adamantyl fluoride

bis(pentafluorophenyl)borohydride