{N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)}

Base Information

• Chemical Name: {N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)}
• CAS No.: 80612-33-5
• Molecular Formula: C₈H₂₀N*C₂₁H₁₆FeO₃P
• Molecular Weight: 533.43
• Mol file: 80612-33-5.mol

Synonyms:{N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)}

Chemical Property of {N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of {N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)}

There total 4 articles about {N(C₂H₅)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)3)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)3)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

K2[Fe(CO)3(PPh3)] (80612-34-6) + tetraethylammonium bromide (71-91-0) + acetonitrile (75-05-8,26809-02-9) → {Et4N}{HFe(CO)3PPh3} (80612-33-5)

Guidance literature:

In acetonitrile; Fe-complex reacted with CH3CN, cation exchanged with Et4NBr;

DOI:10.1021/ja00368a059

Reference yield: 89.0%

tetraethylammonium hydroxide + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) → {N(C2H5)4}(1+)*{HFe(CO)3(P(C6H5)3)}(1-)={N(CH2CH3)4}{HFe(CO)3(P(C6H5)3)} (80612-33-5)

Guidance literature:

In methanol; byproducts: CO2; adding oxygen-free 25% CH3OH soln. of (Et4N)(OH) to solid Fe(CO)4PPh3, stirring (20 min), slowy removing CH3OH (vacuum), gas evolution (10 h); rinsing (ethanol, hexane, THF), recrystn. (acetone-Et2O); elem. anal.;

Reference yield:

tetraethylammonium hydroxide + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) → {Et4N}{HFe(CO)3PPh3} (80612-33-5)

Guidance literature:

In methanol; Fe-complex treated with 15 equiv of Et4NOH in MeOH, 24 h at room temp.,most of solvent removed under vac. at or slightly below room temp.; elem. anal.;

DOI:10.1021/ja00368a059

upstream raw materials:

tetracarbonyl(triphenylphosphine)iron

K₂[Fe(CO)3(PPh₃)]

tetraethylammonium bromide

acetonitrile

Downstream raw materials:

pentacarbonylmanganate

pentacarbonylhydridomanganese

tetracarbonyl(triphenylphosphine)iron

trans-Fe(CO)₃(triphenylphosphine)₂