l-menthone enol trimethylsilyl ether

Base Information

Chemical Name:l-menthone enol trimethylsilyl ether
CAS No.:74173-21-0
Molecular Formula:C₁₃H₂₆OSi
Molecular Weight:226.434
Hs Code.:

Synonyms:l-menthone enol trimethylsilyl ether

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Chemical Property of l-menthone enol trimethylsilyl ether

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Technology Process of l-menthone enol trimethylsilyl ether

There total 1 articles about l-menthone enol trimethylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.1%

: 75-77-4
chloro-trimethyl-silane

: 10458-14-7,14073-97-3,17627-49-5,7786-64-3
(2R,5S)-menthone

: 74173-21-0
l-menthone enol trimethylsilyl ether

Guidance literature:: With triethylamine; In N,N-dimethyl-formamide; at 150 ℃; for 47h;

Reference yield:

: 74173-21-0
l-menthone enol trimethylsilyl ether

: 10458-14-7,14073-97-3,17627-49-5,7786-64-3
(2R,5S)-menthone

: 1196-31-2,17627-49-5,7786-64-3
(1R,4R)-(+)-isomenthone

Guidance literature:: With n-butyllithium; (1R,3S,5R)-1,3,5-trimethyl-5-<(4S,5S)-4,5-diphenyl-Δ²-oxazolin-2-yl>cyclohexane-1,3-dicarboxylic acid imide; In tetrahydrofuran; at -78 ℃; for 2h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1055/s-1997-6131

Reference yield:

: 74173-21-0
l-menthone enol trimethylsilyl ether

: 205177-22-6
E-3-isopropyl-6R-methylcyclohept-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: diethylzinc / hexane / 0 - 25 °C / Inert atmosphere

2: iron(III) chloride / N,N-dimethyl-formamide / 4 h / 0 °C / Inert atmosphere

3: sodium acetate / methanol / 25 - 80 °C / Inert atmosphere

With iron(III) chloride; diethylzinc; sodium acetate; In methanol; hexane; N,N-dimethyl-formamide; 1: Simmons-Smith cyclopropanation;
DOI:10.1002/anie.201100926