6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

Base Information

Chemical Name:6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene
CAS No.:145386-69-2
Molecular Formula:C₁₆H₃₄O₂Si₂
Molecular Weight:314.616
Hs Code.:

Synonyms:6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

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Chemical Property of 6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

Chemical Property:

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Technology Process of 6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

There total 4 articles about 6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 832131-69-8
(+/-)-cis/trans-2-{[(tert-butyl)(dimethyl)silyloxy]methyl}cyclohexanol

: 145386-69-2
6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1.1: silica gel; pyridinium chlorochromate / dichloromethane / 14 h / 20 °C / Inert atmosphere

2.1: n-butyllithium; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; silica gel; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201007135

Reference yield:

: 930-68-7
cyclohexenone

: 145386-69-2
6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1.1: iodine; magnesium / tetrahydrofuran / 14 h / 66 °C / Inert atmosphere

1.2: 6 h / 20 °C / Inert atmosphere

2.1: silica gel; pyridinium chlorochromate / dichloromethane / 14 h / 20 °C / Inert atmosphere

3.1: n-butyllithium; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; iodine; silica gel; magnesium; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201007135

Reference yield:

: 140139-05-5
bromomethoxy(t-butyl)dimethylsilane

: 145386-69-2
6-[(tert-butyldimethylsilyloxy)methyl]-1-trimethylsilyloxy-1-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1.1: iodine; magnesium / tetrahydrofuran / 14 h / 66 °C / Inert atmosphere

1.2: 6 h / 20 °C / Inert atmosphere

2.1: silica gel; pyridinium chlorochromate / dichloromethane / 14 h / 20 °C / Inert atmosphere

3.1: n-butyllithium; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; iodine; silica gel; magnesium; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201007135