(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

Base Information

Chemical Name:(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester
CAS No.:84132-70-7
Molecular Formula:C₁₇H₂₆O₄Si
Molecular Weight:322.477
Hs Code.:

Synonyms:(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

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Chemical Property of (E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

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Technology Process of (E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

There total 4 articles about (E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 84132-56-9
3-cyclohex-2-en-1-ol

: 26367-48-6
fumaric acid ethyl ester mono chloride

: 84132-70-7
(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

Guidance literature:: In tetrahydrofuran; pyridine; at 25 ℃; for 14.5h;
DOI:10.1021/jo00152a009

Reference yield:

: 16807-60-6
3-methoxycyclohex-2-en-1-one

: 84132-70-7
(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / tetrahydrofuran / 1.) -78 degC, 2.) 4,5 h, room temp.,

2: 97 percent / LiAlH₄ / diethyl ether / 1.75 h / -20 °C

3: 87 percent / tetrahydrofuran; pyridine / 14.5 h / 25 °C

With lithium aluminium tetrahydride; In tetrahydrofuran; pyridine; diethyl ether;
DOI:10.1021/jo00152a009

Reference yield:

: 84132-55-8
3-cyclohex-2-en-1-one

: 84132-70-7
(E)-But-2-enedioic acid ethyl ester 3-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / LiAlH₄ / diethyl ether / 1.75 h / -20 °C

2: 87 percent / tetrahydrofuran; pyridine / 14.5 h / 25 °C

With lithium aluminium tetrahydride; In tetrahydrofuran; pyridine; diethyl ether;
DOI:10.1021/jo00152a009