cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

Base Information

Chemical Name:cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]
CAS No.:88666-22-2
Molecular Formula:C₂₄H₂₀MnO₅P
Molecular Weight:474.332
Hs Code.:

cis-[Mn(CO)4(PPh<sub>3</sub>)(CH<sub>2</sub>OCH<sub>3</sub>)]

Synonyms:cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

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Chemical Property of cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

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Technology Process of cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

There total 3 articles about cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 57693-96-6,65437-12-9,13682-00-3
{(PPh₃)manganese(carbonyl)4 bromide}

: 107-30-2
chloromethyl methyl ether

: 88666-22-2
cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

Guidance literature:: With Na/Hg; In tetrahydrofuran; (N2); std. Schlenk technique; soln. of Mn complex in THF was slowly added to Na/Hg (4 equiv.); stirred in dark for 2 d; decanted into soln. of ClCH2OCH3 in THF; stirred in dark for 2 h; evapd.; dissolved in THF; filtered; recrystd. (THF/petroleum ether); dried (vac.);
DOI:10.1021/om900804j

Reference yield:

: 67-56-1
methanol

: 54039-46-2
pentacarbonyl(triphenylphosphine)manganese tetrafluoroborate

: 146283-26-3
[HPt(1,2-bis(dimethylphosphino)ethane)₂][PF₆]

: 88666-22-2
cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

Guidance literature:: With CF₃C₆H₄SO₃H; In methanol; (N2); std. Schlenk technique; MeOH was added to mixt. of Mn complex and Pt complex (1.2 equiv.) at -78°C; stirred for 15 min; soln. of acid (2.2 equiv.) in MeOH was added; warmed to room temp.; stirred for 1 h; evapd. (vac.); dissolved in C6H6; filtered through Celite; evapd.; triturated with pentane;
DOI:10.1021/om900804j

Reference yield:

: [Mn(CO)3(P(C₆H₅)3)2(CHOCH₃)]⁽¹⁺⁾*O₃SCF₃^(1-)=[Mn(CO)3(P(C₆H₅)3)2(CHOCH₃)][O₃SCF₃]

: 88666-22-2
cis-[Mn(CO)4(PPh₃)(CH₂OCH₃)]

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: benzene-d6

In tetrahydrofuran; benzene-d6;
DOI:10.1021/om900804j