2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

Base Information

Chemical Name:2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester
CAS No.:286930-15-2
Molecular Formula:C₃₂H₅₁ClO₆SSi
Molecular Weight:627.358
Hs Code.:

Synonyms:2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

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Chemical Property of 2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

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Technology Process of 2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

There total 4 articles about 2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 286930-14-1
(2R,3R,8R,4E,6E)-8-tert-butyldimethylsilyloxy-2-chloroacetoxy-3-phenylthiotrideca-4,6-dienyl 2,2-dimethylpropanoate

: 286930-15-2
2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃;
DOI:10.1016/S0040-4039(00)00434-2

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 286930-15-2
2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 125 mg

2: 95 percent / m-CPBA / CH₂Cl₂ / 0.5 h / -78 °C

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo001036c

Reference yield:

: 3282-30-2
pivaloyl chloride

: 286930-15-2
2,2-Dimethyl-propionic acid (4E,6E)-(2R,3R,8R)-3-benzenesulfinyl-8-(tert-butyl-dimethyl-silanyloxy)-2-(2-chloro-acetoxy)-trideca-4,6-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 125 mg

2: 95 percent / m-CPBA / CH₂Cl₂ / 0.5 h / -78 °C

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo001036c