N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide

Base Information

• Chemical Name: N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide
• CAS No.: 64650-83-5
• Molecular Formula: C₁₁H₁₉NO₆
• Molecular Weight: 261.275
• Mol file: 64650-83-5.mol

Synonyms:N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide

Chemical Property of N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide

There total 38 articles about N-((2S,3R,4R,5R,6R)-2-Allyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside (63064-48-2,116288-58-5,117299-90-8,126778-02-7,28738-44-5) → allyl 2-acetamido-2-deoxy-β-D-glucopyranoside (54400-75-8,64650-83-5,88903-97-3,116347-86-5,140849-88-3,144300-01-6,54400-77-0)

Guidance literature:

allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside; With sodium methylate; In methanol; at 20 ℃;

In methanol; pH=7;

DOI:10.1055/s-0036-1591082

Reference yield: 100.0%

allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranoside (28738-44-5,63064-48-2,117299-90-8,126778-02-7,116288-58-5) → allyl-2-acetamido-2-deoxy-β-D-galactopyranoside (54400-75-8,54400-77-0,64650-83-5,88903-97-3,140849-88-3,144300-01-6,116347-86-5)

Guidance literature:

allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranoside; With sodium methylate; In methanol; at 20 ℃;

In methanol; pH=7;

DOI:10.1055/s-0036-1591082

Reference yield: 95.0%

sodium allyloxide (20907-32-8) + Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester (3068-34-6) → allyl 2-acetamido-2-deoxy-β-D-glucopyranoside (54400-75-8,64650-83-5,88903-97-3,116347-86-5,140849-88-3,144300-01-6,54400-77-0)

Guidance literature:

With allyl alcohol; at 20 ℃; for 0.5h;

DOI:10.1080/07328309908544034

upstream raw materials:

allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline

N-Acetyl-D-glucosamine

allyl alcohol

Downstream raw materials:

allyl 2-deoxy-2-acetamido-4,6-O-benzylidene-β-D-glucopyranoside

allyl 2-acetamido-2-deoxy-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranoside

allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

2-propenyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside