Mo(NO)Cl₃(NCMe)2

Base Information

• Chemical Name: Mo(NO)Cl₃(NCMe)2
• CAS No.: 65060-56-2
• Molecular Formula: C₄H₆Cl₃MoN₃O
• Molecular Weight: 314.41
• Mol file: 65060-56-2.mol

Synonyms:Mo(NO)Cl₃(NCMe)2

Chemical Property of Mo(NO)Cl₃(NCMe)2

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Mo(NO)Cl₃(NCMe)2

There total 1 articles about Mo(NO)Cl₃(NCMe)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

molybdenum(V) chloride (10241-05-1) + nitrogen(II) oxide (10102-43-9) + acetonitrile (75-05-8,26809-02-9) → Mo(NO)Cl3(NCMe)2 (65060-56-2) + nitrosylchloride (2696-92-6)

Guidance literature:

In dichloromethane; NO was bubbled through the soln. of MoCl5 and CH3CN at room temp. for 1h, Ar atm.; concn., pptn. with pentane, filtration, washing with pentane, drying invac.; elem. anal.;

DOI:10.1016/S0020-1693(00)93479-0

Reference yield: 86.0%

Mo(NO)Cl3(NCMe)2 (65060-56-2) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Mo(NO)(2,2'-bis(diphenylphosphino)diphenylether)Cl2]2[μCl]2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/cs4004276

Reference yield: 60.0%

Mo(NO)Cl3(NCMe)2 (65060-56-2) → MoCl(CO)2(NO)(P(C6H5)3)2 + molybdenum hexacarbonyl (13939-06-5,199620-15-0)

Guidance literature:

With carbon monoxide; ethylaluminum dichloride; triphenylphosphine; In benzene; a vigorously stirred suspn. of Mo-complex in benzene was treated with 5equiv of EtAlCl2 in benzene under CO atmosphere for 1 h, a benzene soln. of PPh3 was added, mixt. was stirred for addnl. 30 min; reaction was monitored by IR spectroscopy; solvent was evapd. in vacuo at 50°C, residue dissolved in CH2Cl2, detailed isolation of the product is described in the paper by K. Seyferth, R. Taube, L. Bencze and L. Marko, J. Organomet. Chem., 137 (1977) 275; identified by IR spectrum;

DOI:10.1016/S0022-328X(00)99141-1

upstream raw materials:

molybdenum(V) chloride

nitrogen(II) oxide

acetonitrile

Downstream raw materials:

molybdenum hexacarbonyl