C₃₈H₂₃BrN₄Ni

Base Information

• Chemical Name: C₃₈H₂₃BrN₄Ni
• CAS No.: 67108-96-7
• Molecular Formula: C₃₈H₂₃BrN₄Ni
• Molecular Weight: 674.221
• Mol file: 67108-96-7.mol

Synonyms:C₃₈H₂₃BrN₄Ni

Chemical Property of C₃₈H₂₃BrN₄Ni

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₈H₂₃BrN₄Ni

There total 10 articles about C₃₈H₂₃BrN₄Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(5,10,15-triphenylporphyrinato)nickel(II) (67108-97-8) → C38H23BrN4Ni (67108-96-7)

Guidance literature:

With N-Bromosuccinimide; In methanol; dichloromethane; at 20 ℃; for 0.166667h;

DOI:10.1055/s-0030-1259101

Reference yield: 92.0%

(5,10,15-triphenylporphyrinato)nickel(II) (67108-97-8) → (5-bromo-10,15,20-triphenylporphyrinato)nickel(II) (67108-96-7)

Guidance literature:

With pyridine; N-Bromosuccinimide; In chloroform;

DOI:10.1002/ejoc.201201535

Reference yield: 92.0%

5-bromo-10,20-dihexyl-15-phenylporphyrin (5) (67066-09-5) + bis(acetylacetonate)nickel(II) → (5-bromo-10,15,20-triphenylporphyrinato)nickel(II) (67108-96-7)

Guidance literature:

Reflux;

DOI:10.1039/c8ob00174j

upstream raw materials:

(5,10,15-triphenylporphyrinato)nickel(II)

5,15-diphenylporphyrin

phenyllithium

5-bromo-10,20-dihexyl-15-phenylporphyrin (5)

Downstream raw materials:

[5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-10,15,20-triphenylporphyrinato]nickel(II)

[5,10,15-triphenyl-20-propadienylporphyrinato]nickel(II)

C₄₁H₂₆N₄Ni