(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

Base Information

Chemical Name:(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol
CAS No.:132164-03-5
Molecular Formula:C₄₁H₄₀O₄
Molecular Weight:596.766
Hs Code.:

Synonyms:(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

Suppliers and Price of (1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

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Technology Process of (1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

There total 10 articles about (1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 160549-10-0
2,3,5-tri-O-benzyl-D-arabinofuranose

: 132164-03-5
(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

Guidance literature:: Multi-step reaction with 7 steps

1: 92 percent / CH₂Cl₂ / 25 °C

2: DMSO/(COCl)2, EtN₃

3: 93 percent / CF₃COOH / CH₂Cl₂ / 0 °C

4: 1.) LDA; 2.) LDA / 2.) -78 deg C

5: Bu₃SnH / benzene / 25 °C

7: AcOH

With oxalyl dichloride; tri-n-butyl-tin hydride; acetic acid; dimethyl sulfoxide; trifluoroacetic acid; lithium diisopropyl amide; ethyl azide; In dichloromethane; benzene;
DOI:10.1021/ja00271a049

Reference yield:

: 101916-96-5
(Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-D-threo-hept-2-en-6-ulosonic acid

: 132164-03-5
(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA; 2.) LDA / 2.) -78 deg C

2: Bu₃SnH / benzene / 25 °C

4: AcOH

With tri-n-butyl-tin hydride; acetic acid; lithium diisopropyl amide; In benzene;
DOI:10.1021/ja00271a049

Reference yield:

: 101916-94-3
tert-butyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-D-threo-hept-2-en-6-ulosonate

: 132164-03-5
(1S,2S,3R,4R)-2,3-bis(benzyloxy)-1-<(benzyloxy)methyl>-4-(2,2-diphenylvinyl)cyclopentanol

Guidance literature:: Multi-step reaction with 5 steps

1: 93 percent / CF₃COOH / CH₂Cl₂ / 0 °C

2: 1.) LDA; 2.) LDA / 2.) -78 deg C

3: Bu₃SnH / benzene / 25 °C

5: AcOH

With tri-n-butyl-tin hydride; acetic acid; trifluoroacetic acid; lithium diisopropyl amide; In dichloromethane; benzene;
DOI:10.1021/ja00271a049