(N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II)

Base Information

• Chemical Name: (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II)
• CAS No.: 922495-52-1
• Molecular Formula: C₂₈H₂₄N₂O₂Pt
• Molecular Weight: 615.591
• Mol file: 922495-52-1.mol

Synonyms:(N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II)

Chemical Property of (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II)

There total 5 articles about (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

N-(4-(pyridin-2-yl)phenyl)-N,N-diphenylamine (140947-06-4) + potassium tetrachloroplatinate(II) (10025-99-7) + acetylacetone (123-54-6,81235-32-7) → (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II) (922495-52-1)

Guidance literature:

With Na₂CO₃; In 2-ethoxy-ethanol; water; (under N2, Schlenk); mixt. of ligand, K2PtCl4 stirred in 2-ethoxyethanol-H2O, heated at 80°C for 16 h, cooled to room temp., H2O added, ppt. washed with H2O, vac. dried, reacted with acetylacetone, Na2CO3 at 100°C for 20 h; solvent removed under reduced pressure, residue purified with TLC on silica with CH2Cl2; elem. anal.;

DOI:10.1021/ic061566c

Reference yield:

C46H34Cl2N4Pt2 (932021-82-4) + acetylacetone (123-54-6,81235-32-7) → (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II) (922495-52-1)

Guidance literature:

With sodium carbonate; In 2-ethoxy-ethanol; at 100 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.dyepig.2013.09.030

Reference yield:

2-bromo-pyridine (109-04-6) → (N,N-diphenyl-4-(2-pyridyl)benzeneamine)(acetylacetonato)platinum(II) (922495-52-1)

Guidance literature:

Multi-step reaction with 3 steps

1: palladium diacetate; potassium carbonate / ethanol; water / 80 °C

2: water; 2-ethoxy-ethanol / 80 °C / Inert atmosphere

3: sodium carbonate / 2-ethoxy-ethanol / 24 h / 100 °C / Inert atmosphere

With palladium diacetate; sodium carbonate; potassium carbonate; In 2-ethoxy-ethanol; ethanol; water; 1: |Suzuki Coupling;

DOI:10.1016/j.dyepig.2013.09.030

upstream raw materials:

N-(4-(pyridin-2-yl)phenyl)-N,N-diphenylamine

potassium tetrachloroplatinate(II)

acetylacetone

4-(diphenylamino)phenyl boronic acid