[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

Base Information

Chemical Name:[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl
CAS No.:671789-64-3
Molecular Formula:C₃₀H₄₂ClF₆IrO₂P₂
Molecular Weight:838.273
Hs Code.:

[4-(3,5-bis(trifluoromethyl)phenyl)C<sub>6</sub>H<sub>3</sub>-2,6-(OP(tBu)2)2]IrHCl

Synonyms:[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

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Chemical Property of [4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

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Technology Process of [4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

There total 1 articles about [4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 671235-36-2
p-(3,5-bis(trifluoromethyl)phenyl)-C₆H₃(OP(tert-butyl)2)2

: 671789-64-3
(η3-p-(3,5-bis(trifluoromethyl)phenyl)C6H2(OP(tert-butyl)2)2)IrHCl

Guidance literature:: In toluene; Ar; addn. of toluene to Ar-filled flask contg. 0.5 equiv. of Ir complex and 1.1 equiv. of ligand, stirred at 150°C (oil bath) for 2 h; rapidly cooled to 30°C, evapd. under vac., residue extd. with pentane under ultrasound, filtration, solid washed with pentane, dried under high vac., further crop of product obtained by chromy. of filtrate (hexanes/Et2O 20/1); elem. anal.;
DOI:10.1021/ja0385235

Reference yield: 93.0%

: 671789-64-3
[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

: 1333-74-0
hydrogen

: [p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₄

: 686274-20-4
[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

Guidance literature:: With tert-C₄H₉ONa; In benzene; byproducts: NaCl, t-BuOH; 1 equiv of complex and 1.1 equiv of NaOt-Bu were dissolved in N2-free benzene, the flask was purged with H2, the soln. was stirred for 0.5-1.5 hat 23°C under slow flow of H2; the mixt. was cooled to 0°C, the solvent was removed in vac. (1E-3 mbar, 3 h), Ar and N2-free pentane were added, filtered, the solvent was removed in vac., the residue was dissolved in N2-free C6H6, sublimed at 0°C for 2 h; elem. anal.;
DOI:10.1021/om030670o

Reference yield: 76.0%

: 671789-64-3
[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

: 7727-37-9
nitrogen

: 108-88-3,15644-74-3,16713-13-6
toluene

: [(4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2)Ir]2N₂-toluene (1:2)

Guidance literature:: With tert-C₄H₉ONa; In toluene; a soln. of complex and NaOBu-t in toluene was stirred under N2 atm for 60 min at 23°C; solvent was removed in vac., extd. with pentane, evapd., recrystd. from refluxing toluene under N2, dried under high vac.; elem. anal.;
DOI:10.1021/om030670o