2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

Base Information

Chemical Name:2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone
CAS No.:357172-73-7
Molecular Formula:C₁₈H₂₆O₅
Molecular Weight:322.401
Hs Code.:

Synonyms:2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

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Chemical Property of 2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

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Technology Process of 2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

There total 8 articles about 2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 357172-71-5
(S)-4-(2,5-Dimethoxy-3,4,6-trimethyl-phenyl)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butan-2-ol

: 357172-73-7
2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

Guidance literature:: With ammonium cerium(IV) nitrate; In acetonitrile;
DOI:10.1055/s-2001-14642

Reference yield:

: 25691-80-9
1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propenone

: 357172-73-7
2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

Guidance literature:: Multi-step reaction with 3 steps

1.1: Mg; (CH₂Br)2 / tetrahydrofuran / Heating

1.2: 64 percent / CuI; Me₃SiCl / tetrahydrofuran; hexamethylphosphoric acid triamide / -70 °C

2.1: SnCl₄ / CH₂Cl₂ / -70 °C

3.1: 100 percent / Ce(NH₄)2(NO₃)6 / acetonitrile

With ammonium cerium(IV) nitrate; tin(IV) chloride; magnesium; ethylene dibromide; In tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1055/s-2001-14642

Reference yield:

: 700-13-0
Trimethylhydroquinone

: 357172-73-7
2-[(S)-3-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-butyl]-3,5,6-trimethyl-[1,4]benzoquinone

Guidance literature:: Multi-step reaction with 5 steps

1.1: (n-Bu)4NI; aq. KOH / 20 °C

2.1: 100 percent / Br₂ / CCl₄ / 0 °C

3.1: Mg; (CH₂Br)2 / tetrahydrofuran / Heating

3.2: 64 percent / CuI; Me₃SiCl / tetrahydrofuran; hexamethylphosphoric acid triamide / -70 °C

4.1: SnCl₄ / CH₂Cl₂ / -70 °C

5.1: 100 percent / Ce(NH₄)2(NO₃)6 / acetonitrile

With potassium hydroxide; ammonium cerium(IV) nitrate; bromine; tin(IV) chloride; tetra-(n-butyl)ammonium iodide; magnesium; ethylene dibromide; In tetrahydrofuran; tetrachloromethane; dichloromethane; acetonitrile;
DOI:10.1055/s-2001-14642