5a-carba-α-D-mannopyranose

Base Information

• Chemical Name: 5a-carba-α-D-mannopyranose
• CAS No.: 135820-00-7
• Molecular Formula: C₇H₁₄O₅
• Molecular Weight: 178.185
• Mol file: 135820-00-7.mol

Synonyms:5a-carba-α-D-mannopyranose

Chemical Property of 5a-carba-α-D-mannopyranose

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 5a-carba-α-D-mannopyranose

There total 101 articles about 5a-carba-α-D-mannopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(1S,2R,3S,4R,5R)-2,3,4-tris(benzyloxy)-5-(benzyloxymethyl)-cyclohexanol (1151903-44-4) → 5a-carba-α-D-mannopyranose (135820-00-7)

Guidance literature:

With hydrogen; palladium(II) hydroxide; In water; isopropyl alcohol; for 48h;

DOI:10.1016/j.carres.2011.04.011

Reference yield: 100.0%

(1S,2R,3S,4R,5R)-3-O-Benzyl-5-benzyloxymethyl-cyclohexan-1,2,3,4-tetraol (135735-95-4,141661-68-9) → 5a-carba-α-D-mannopyranose (135820-00-7)

Guidance literature:

With hydrogen; palladium dihydroxide; In ethanol;

DOI:10.1039/c39910000756

Reference yield: 100.0%

(1S,2R,3R,4R,5R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-cyclohexane-1,2-diol (207564-36-1) → 5a-carba-α-D-mannopyranose (135820-00-7)

Guidance literature:

With hydrogen; palladium dihydroxide; for 2h; under 2844.3 Torr;

DOI:10.1039/a801989d

upstream raw materials:

Pseudo-β-DL-gulopyranose-pentaacetat; DL-1-Acetoxymethyl-2,3,4,5-tetraacetoxy-cyclohexan

DL-2,5-Diacetoxy-1-acetoxymethyl-cyclohexen-⁽³⁾

Pseudo-β-DL-gulopyranose-triacetat; DL-1-Acetoxymethyl-2,5-diacetoxy-3,4-dihydroxy-cyclohexan

DL-(1/2,3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol

Downstream raw materials:

DL-(1,2/3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol

5a-carba-α-D-mannopyranose-6-phosphate

DL-(1,5/2,3,4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol

DL-(1,5/2,3,4)-5-acetoxymethyl-1,2,3,4-tetra-acetoxycyclohexane