C₃₃H₅₁IO₂Si₂

Base Information

• Chemical Name: C₃₃H₅₁IO₂Si₂
• CAS No.: 1026106-25-1
• Molecular Formula: C₃₃H₅₁IO₂Si₂
• Molecular Weight: 662.842
• Mol file: 1026106-25-1.mol

Synonyms:C₃₃H₅₁IO₂Si₂

Chemical Property of C₃₃H₅₁IO₂Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₃₃H₅₁IO₂Si₂

There total 1 articles about C₃₃H₅₁IO₂Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C27H36O2Si (1026106-23-9) + tert-butyldimethylsilyl chloride (18162-48-6) → C33H51IO2Si2 (1026106-25-1)

Guidance literature:

C₂₇H₃₆O₂Si; With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In tetrahydrofuran; at 65 ℃;

tert-butyldimethylsilyl chloride; With dmap; triethylamine; In dichloromethane;

With iodine; In dichloromethane; at 0 ℃; Further stages.;

DOI:10.1016/j.tetlet.2008.02.168

Reference yield: 55.0%

C33H51IO2Si2 (1026106-25-1) + carbon monoxide (201230-82-2) → C33H50O2Si2 (1026106-27-3) + C34H50O3Si2 (1026106-26-2)

Guidance literature:

With potassium phosphate; bis-triphenylphosphine-palladium(II) chloride; In 1,4-dioxane; at 70 ℃; for 12h; under 3000.3 Torr;

DOI:10.1016/j.tetlet.2008.02.168

Reference yield: 47.0%

C33H51IO2Si2 (1026106-25-1) + carbon monoxide (201230-82-2) → C33H50O2Si2 (1026106-27-3) + C34H50O3Si2 (1026106-26-2) + C34H52O4Si2 (1026106-28-4)

Guidance literature:

With potassium phosphate; tricyclohexylphosphine; palladium diacetate; In 1,4-dioxane; toluene; at 70 ℃; for 12h; under 3000.3 Torr;

DOI:10.1016/j.tetlet.2008.02.168

upstream raw materials:

C₂₇H₃₆O₂Si

tert-butyldimethylsilyl chloride

Downstream raw materials:

C₃₄H₅₀O₃Si₂

C₃₃H₅₀O₂Si₂

C₃₄H₅₂O₄Si₂