[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

Base Information

Chemical Name:[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane
CAS No.:226879-36-3
Molecular Formula:C₄₅H₅₈O₅S₂Si
Molecular Weight:771.17
Hs Code.:

[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-<i>tert</i>-butyl-diphenyl-silane

Synonyms:[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

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Chemical Property of [6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

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Technology Process of [6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

There total 7 articles about [6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 100-39-0
benzyl bromide

: 226879-35-2
{2-[6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-hex-3-enyl]-[1,3]dithian-2-yl}-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methanol

: 226879-36-3
[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: With sodium hydride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(99)00323-8

Reference yield:

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 226879-36-3
[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 80 percent / diethyl ether

2.1: 80 percent / PrCOOH / 140 °C

3.1: 95 percent / DIBALH / CH₂Cl₂

4.1: 80 percent / BF₃*Et₂O / CH₂Cl₂

5.1: BuLi / tetrahydrofuran / 0.5 h / 0 - 23 °C

5.2: 80 percent / tetrahydrofuran / 1 h / -78 °C

6.1: 82 percent / NaH / tetrahydrofuran

With n-butyllithium; boron trifluoride diethyl etherate; sodium hydride; diisobutylaluminium hydride; butyric acid; In tetrahydrofuran; diethyl ether; dichloromethane; 1.1: Grignard reaction / 2.1: Condensation / 3.1: Reduction / 4.1: Condensation / 5.1: Metallation / 5.2: Addition / 6.1: Substitution;
DOI:10.1016/S0040-4039(99)00323-8

Reference yield:

: 127047-71-6
3-(tert-butyldiphenylsilyloxy)propan-1-ol

: 226879-36-3
[6-(2-{benzyloxy-[5-(tetrahydro-pyran-2-yloxymethyl)-furan-2-yl]-methyl}-[1,3]dithian-2-yl)-4-methyl-hex-3-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 7 steps

1.1: 95 percent / (COCl)2; Et₃N; DMSO / CH₂Cl₂ / -78 °C

2.1: 80 percent / diethyl ether

3.1: 80 percent / PrCOOH / 140 °C

4.1: 95 percent / DIBALH / CH₂Cl₂

5.1: 80 percent / BF₃*Et₂O / CH₂Cl₂

6.1: BuLi / tetrahydrofuran / 0.5 h / 0 - 23 °C

6.2: 80 percent / tetrahydrofuran / 1 h / -78 °C

7.1: 82 percent / NaH / tetrahydrofuran

With n-butyllithium; oxalyl dichloride; boron trifluoride diethyl etherate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; butyric acid; In tetrahydrofuran; diethyl ether; dichloromethane; 1.1: Oxidation / 2.1: Grignard reaction / 3.1: Condensation / 4.1: Reduction / 5.1: Condensation / 6.1: Metallation / 6.2: Addition / 7.1: Substitution;
DOI:10.1016/S0040-4039(99)00323-8