1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾

Base Information

• Chemical Name: 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾
• CAS No.: 17444-22-3
• Molecular Formula: C₈H₁₅B₁₀I
• Molecular Weight: 346.222
• Mol file: 17444-22-3.mol

Synonyms:1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾

Chemical Property of 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾

There total 5 articles about 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane⁽¹²⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

1-phenyl-1,2-closo-C2B10H11 (16390-61-7) + Iodine monochloride (7790-99-0) → 1-phenyl 9-iodo 1,2-dicarba-closo-dodecaborane(12) (17444-21-2) + 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane(12) (17444-22-3)

Guidance literature:

With methanesulfonic acid; at 60 ℃;

DOI:10.1021/ic5014494

Reference yield:

1-phenyl-1,2-closo-C2B10H11 (16390-61-7) + iodine (7553-56-2,12190-71-5,8031-47-8) → 1-phenyl 9-iodo 1,2-dicarba-closo-dodecaborane(12) (17444-21-2) + 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane(12) (17444-22-3)

Guidance literature:

In neat (no solvent); at 120 ℃; for 1.25h; Overall yield = 75 %; Overall yield = 59 mg; Inert atmosphere;

DOI:10.1016/j.jorganchem.2015.05.053

Reference yield:

1-phenyl-1,2-closo-C2B10H11 (16390-61-7) + iodine (7553-56-2,12190-71-5,8031-47-8) → 1-phenyl 12-iodo 1,2-dicarba-closo-dodecaborane(12) (17444-22-3)

Guidance literature:

iron; In tetrachloromethane; calcd. amounts of I2; 40-80°C;; separation by chromatography; crystn. or sublimation;;

upstream raw materials:

1-phenyl-1,2-closo-C₂B₁₀H₁₁

iodine

1-iodo decaborane⁽¹⁴⁾

phenylacetylene