Technology Process of N,N',N''-tris(4-hydroxyphenyl)-1,8,13-triptycenetricarboxamide
There total 6 articles about N,N',N''-tris(4-hydroxyphenyl)-1,8,13-triptycenetricarboxamide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triethylamine;
In
dichloromethane;
for 18h;
Heating;
DOI:10.1021/jo00367a011
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 92 percent / H2 / 5percent Pd/C / methanol / 8 h / 2068.6 Torr / Ambient temperature
2: isoamyl nitrite / 1,2-dimethoxy-ethane / 1 h / Heating
3: 95 percent / 10percent KOH / methanol / 12 h / Heating
4: 98 percent / SOCl2 / 12 h / Heating
5: 95 percent / Et3N / CH2Cl2 / 18 h / Heating
With
potassium hydroxide; thionyl chloride; hydrogen; triethylamine; isopentyl nitrite;
palladium on activated charcoal;
In
methanol; 1,2-dimethoxyethane; dichloromethane;
DOI:10.1021/jo00367a011
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 77 percent / HCl / methanol / Heating
2: 92 percent / H2 / 5percent Pd/C / methanol / 8 h / 2068.6 Torr / Ambient temperature
3: isoamyl nitrite / 1,2-dimethoxy-ethane / 1 h / Heating
4: 95 percent / 10percent KOH / methanol / 12 h / Heating
5: 98 percent / SOCl2 / 12 h / Heating
6: 95 percent / Et3N / CH2Cl2 / 18 h / Heating
With
hydrogenchloride; potassium hydroxide; thionyl chloride; hydrogen; triethylamine; isopentyl nitrite;
palladium on activated charcoal;
In
methanol; 1,2-dimethoxyethane; dichloromethane;
DOI:10.1021/jo00367a011
