(2-methylphenyl)triphenylbismuthonium tetrafluoroborate

Base Information

Chemical Name:(2-methylphenyl)triphenylbismuthonium tetrafluoroborate
CAS No.:214141-51-2
Molecular Formula:BF₄*C₂₅H₂₂Bi
Molecular Weight:618.235
Hs Code.:

Synonyms:(2-methylphenyl)triphenylbismuthonium tetrafluoroborate

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Chemical Property of (2-methylphenyl)triphenylbismuthonium tetrafluoroborate

Chemical Property:

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Technology Process of (2-methylphenyl)triphenylbismuthonium tetrafluoroborate

There total 1 articles about (2-methylphenyl)triphenylbismuthonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 13755-29-8
sodium tetrafluoroborate

: 16419-60-6
2-Methylphenylboronic acid

: 2023-48-5,28719-53-1
triphenylbismuth(V) difluoride

: 214141-51-2
(2-methylphenyl)triphenylbismuthonium tetrafluoroborate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; water; stirring (room temp., 2 h), NaBF4 soln. (H2O) addn., stirring (30 min); extg. (CH2Cl2), drying (MgSO4), filtering, evapn. (reduced pressure), crystn. (Et2O / CH2Cl2 = 10 : 1);
DOI:10.1021/om9804531

Reference yield:

: 214141-51-2
(2-methylphenyl)triphenylbismuthonium tetrafluoroborate

: diphenyl(2-methylphenyl)bismuthane

: 603-33-8
triphenylbismuthane

Guidance literature:: With geraniol; N,N,N',N'-tetramethylguanidine; In dichloromethane; byproducts: geranial, benzene, toluene; addn. of N,N,N'N'-tetramethylguanidine (0.02 mmol) to mixt. of (2-MeC6H4)Ph3Bi)(BF4) (0.02 mmol), geraniol (0.02 mmol) and CH2Cl2 at 24°C; stirring at the same temp.; GC analysis; concn. under reduced pressure, addn. of CDCl3; monitoring by NNR;
DOI:10.1246/bcsj.81.1621

Reference yield:

: 214141-51-2
(2-methylphenyl)triphenylbismuthonium tetrafluoroborate

: 214141-61-4
mesityltriphenylbismuthonium tetrafluoroborate

: 603-33-8
triphenylbismuthane

Guidance literature:: With geraniol; N,N,N',N'-tetramethylguanidine; In dichloromethane; byproducts: geranial, toluene, mesitylene; addn. of N,N,N'N'-tetramethylguanidine (0.02 mmol) to mixt. of (Bi(mesityl)Ph3)(BF4) and ((2-MeC6H4)Ph3Bi)(BF4) (0.06 mmol each), geraniol (0.02mmol) and CH2Cl2 at 24°C; stirring at the same temp.; GC analysis; concn. under reduced pressure, addn. of CDCl3; monitoring by NNR;
DOI:10.1246/bcsj.81.1621