13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

Base Information

Chemical Name:13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine
CAS No.:1314582-60-9
Molecular Formula:C₂₆H₁₉BrN₂O
Molecular Weight:455.354
Hs Code.:

Synonyms:13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

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Chemical Property of 13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

Chemical Property:

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Technology Process of 13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

There total 3 articles about 13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 1283668-82-5
2-[2-(2-bromophenyl)ethynyl]-5-methoxybenzaldehyde

: 479-27-6
naphthalene-1,8-diamine

: 1314582-60-9
13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

Guidance literature:: With copper(l) iodide; In 1,4-dioxane; at 150 ℃; for 1h; Microwave irradiation;
DOI:10.1016/j.tet.2011.05.051

Reference yield:

: 1015731-95-9
5-methyloxy-2-ethynylbenzaldehyde

: 1314582-60-9
13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 1 h / 80 °C / Inert atmosphere

2: copper(l) iodide / 1,4-dioxane / 1 h / 150 °C / Microwave irradiation

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; 1,4-dioxane; 1: Sonogashira coupling;
DOI:10.1016/j.tet.2011.05.051

Reference yield:

: 583-55-1
1-Bromo-2-iodobenzene

: 1314582-60-9
13-(2-bromophenyl)-9-methoxy-7,7a-dihydroisoquinolino[2,1-a]perimidine

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 1 h / 80 °C / Inert atmosphere

2: copper(l) iodide / 1,4-dioxane / 1 h / 150 °C / Microwave irradiation

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; 1,4-dioxane; 1: Sonogashira coupling;
DOI:10.1016/j.tet.2011.05.051