3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

Base Information

Chemical Name:3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose
CAS No.:1380312-65-1
Molecular Formula:C₃₅H₃₅NO₆S₃
Molecular Weight:661.864
Hs Code.:

Synonyms:3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

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Chemical Property of 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

Chemical Property:

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Technology Process of 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

There total 1 articles about 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69177-83-9,78283-50-8,86495-59-2,114181-97-4,141782-01-6,51173-35-4
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-α-D-xylo-hex-5-enofuranose

: 4832-52-4
tris(phenylthio)methane

: 1380312-65-1
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

: C₃₅H₃₅NO₆S₃

: β-L-idofuranose

Guidance literature:: tris(phenylthio)methane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 4h; Inert atmosphere;

3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-α-D-xylo-hex-5-enofuranose; In tetrahydrofuran; hexane; optical yield given as %de; Inert atmosphere;
DOI:10.1002/ejoc.201200103

Reference yield: 82.0%

: 67-56-1
methanol

: 1380312-65-1
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

: 1380312-66-2
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-5-C-(methoxycarbonyl)-6-nitro-α-D-glucofuranose

Guidance literature:: With boron trifluoride diethyl etherate; water; mercury(II) oxide; In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201200103

Reference yield:

: 1380312-65-1
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-5-C-[tris(phenylthio)methyl]-α-D-glucofuranose

: C₁₅H₁₉NO₈

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate; water; mercury(II) oxide / tetrahydrofuran / 20 °C / Inert atmosphere

2: trifluoroacetic acid / water / 5 h / 20 °C / Inert atmosphere

With boron trifluoride diethyl etherate; water; trifluoroacetic acid; mercury(II) oxide; In tetrahydrofuran; water;
DOI:10.1002/ejoc.201200103