[Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)]

Base Information

• Chemical Name: [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)]
• CAS No.: 138735-97-4
• Molecular Formula: C₄₈H₃₆N₄O₆Ru
• Molecular Weight: 865.907
• Mol file: 138735-97-4.mol

Synonyms:[Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)]

Chemical Property of [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)]

There total 4 articles about [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

dichloro(5,10,15,20-tetra(4-methoxyphenyl)porphyrinato)ruthenium(IV) (1336883-87-4) → [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)] (138735-97-4)

Guidance literature:

dichloro(5,10,15,20-tetra(4-methoxyphenyl)porphyrinato)ruthenium(IV); With AgHalO₃; In acetonitrile; Anaerobic conditions;

In acetonitrile; Anaerobic conditions; Visible light;

DOI:10.1016/j.ica.2011.06.002

Reference yield: 94.0%

dichlorato(5,10,15,20-tetra(4-methoxyphenyl)porphyrinato)ruthenium(IV) (1336883-89-6) → [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)] (138735-97-4)

Guidance literature:

In acetonitrile; Irradiation (UV/VIS); irrdn. soln. of complex in MeCN with 100 W of visible light from tungsten lamp at ambient temp. for approx. 50 min; chromy. (basic Al2O3);

DOI:10.1016/j.ica.2011.06.002

Reference yield:

Ru(5,10,15,20-tetrakis(p-methyxyphenyl)porphyrinato)(CO)(EtOH) (165259-76-7) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → [Ru(VI)(O)2(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate)] (138735-97-4)

Guidance literature:

In not given; N2-atmosphere; elem. anal.;

DOI:10.1021/ic00120a017

upstream raw materials:

Ru(5,10,15,20-tetrakis(p-methyxyphenyl)porphyrinato)(CO)(EtOH)

3-chloro-benzenecarboperoxoic acid

[Ru(C₄₄H₂₄N₄(OCH₃)4)(CO)(CH₃OH)]

dichloro(5,10,15,20-tetra(4-methoxyphenyl)porphyrinato)ruthenium(IV)

Downstream raw materials:

[Ru(IV)(4-OMe-ttp)(NQu)(OH)]

[Ru(IV)(4-OMe-ttp)(NQu)(OEt)]

bis-(4-chloro-phenyl)-diazene

Refernces

• 1、 Vernik, Isak,Stynes, Dennis V.. "Heterotrinuclear Oxo-Bridged FeIIIORuIVOFeIII Complexes of Ruthenium Porphyrin and Borylated Low-Spin Iron Dioximes". . p. 10 - 17. Retrieved 2008/10/08.
• 2、 Ho, Clare,Leung, Wa-Hung,Che, Chi-Ming. "Kinetics of C-H Bond and Alkene Oxidation by trans-Dioxoruthenium(VI) Porphyrins". . p. 2933 - 2940. Retrieved 2007/10/02.