dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron

Base Information

Chemical Name:dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron
CAS No.:85939-52-2
Molecular Formula:C₃₂H₃₁FeO₉P
Molecular Weight:646.413
Hs Code.:

Synonyms:dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron

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Chemical Property of dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron

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Technology Process of dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron

There total 1 articles about dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: C₇H₉Fe(CO)2P(OC₆H₅)3⁽¹⁺⁾*PF₆^(1-) = C₇H₉Fe(CO)2P(OC₆H₅)3(PF₆)

: 18424-76-5
sodiodimethylmalonate

: 85939-52-2
dicarbonyl[dimethyl (2-5-η-cyclohepta-2,4-dienyl)malonate](triphenyl phosphite)iron

Guidance literature:: In not given; by procedure of Pearson, A. J. J. Chem. Soc., Perkin Trans. 1 1977, 2069; purifn. by preparative TLC; elem. anal.;
DOI:10.1021/ja00332a050

Reference yield: 83.0%

: 85939-52-2
Fe(CO)2(P(OC₆H₅)3)(C₇H₉(CH(OOCCH₃)2))

: 1191-15-7
diisobutylaluminium hydride

: 103816-91-7
dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron

Guidance literature:: In tetrahydrofuran; hexane; addn. hexane soln. of Al-compd. to THF soln. of Fe-compd. (-78°C), stirring, (-78°C, 2 h); warming to room temp. (overnight, stirring), addn. of water, stirring (20 min), addn. of Et2O, filtration (Celite), washing (water), drying (MgSO4), filtration, solvent removal, preparative TLC;;

Reference yield: 71.0%

: 16853-85-3
lithium aluminium tetrahydride

: 85939-52-2
Fe(CO)2(P(OC₆H₅)3)(C₇H₉(CH(OOCCH₃)2))

: 103816-91-7
dicarbonyl[1-4-η-5-(1,3-dihydroxy-2-propyl)cyclohepta-1,3-diene](triphenyl phosphite)iron

Guidance literature:: In diethyl ether; addn. of LiAlH4 to soln. of Fe-compd. (0°C); warming to room temp. (overnight, stirring), addn. of water, stirring (15 min), filtration (Celite), washing (water), drying (MgSO4), filtration, solvent removal, flash chromy.; elem. anal.;